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Progress in Chemistry 2012, Vol. Issue (9): 1646-1655 Previous Articles   Next Articles

• Special issues •

Treatment of Waste Water Using Metal-Organic Frameworks

Tong Minman, Zhao Xudong, Xie Liting, Liu Dahuan, Yang Qingyuan, Zhong Chongli   

  1. State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
  • Received: Revised: Online: Published:
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Harmful compounds and heavy metal ions in waste water are often biologically toxic and/or carcinogenic. Thus, removal of these substances from waste water in an efficient way has drawn considerable social and scientific concern in recent years. Metal-organic frameworks (MOFs), commonly recognized as “soft” analogues of zeolites, is a new class of nanoporous materials with various topologies, adjustable pore size, controllable properties, large surface area, as well as acceptable thermal stability. MOFs have received much attention in the fields of chemistry and materials science and have shown potential applications with well performance compared to the traditional porous materials including zeolites and activated carbons, especially in separation. Though gas phase separation using MOFs has been extensively studied and reviewed, studies on liquid phase separation are scarce. This review introduces the research progress on waste water treatment using MOFs, in which different harmful substances such as organic dyes, pharmaceuticals, alcohols, aromatic compounds, heavy metal ions and inorganic ions are included. Detailed analysis of the effect of the pore structure, framework charge and functional group on separation is provided. In addition, future studies that should be focused in this field are proposed based on the existed works combined with the research results in our group. Contents 1 Introduction
2 Metal-organic frameworks for waste water treatment
2.1 Removal of organics
2.2 Removal of inorganics
3 Conclusions and outlook
Key words: metal-organic frameworks, waste water treatment, separation, structure-property relationship

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