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Progress in Chemistry 2011, Vol. 23 Issue (9): 1985-1992 Previous Articles   

Special Issue: 锂离子电池

• Review •

Vanadium-Based Phosphates as Cathode Materials for Lithium Ion Batteries

Ren Manman*, Liu Suwen, Lu Qifang   

  1. Key Laboratory of Processing and Testing Technology of Glass & Functional Ceramic of Shandong Province, Shandong Polytechnic University, Jinan 250353, China
  • Received: Revised: Online: Published:
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Nowadays Li ion batteries have been widely used in many fields as power suppliers for mobile equipment. In commercialized Li ion batteries, cathode materials are mainly lithium transition-metal oxides. However, high cost and security problem limit their large-scale use. Phosphate materials, with a rigid phosphate network and remarkable electrochemical and thermal stability, are considered as a substitution for lithium transition-metal oxides. Among the newly-exploited phosphate cathode materials, vanadium-based phosphates, with stable structure and high theoretical specific capacity, have been attracting much research interest. In this review, recent progress is summarized on the vanadium-based phosphate cathode materials for lithium ion batteries, particularly focusing on the structure, preparation methods, and electrochemical performances of this series of materials. Also, the strategies and the corresponding mechanisms are discussed for the improvement of their general performances.

Contents
1 Introduction
2 Structure characterization and electrochemical perf-ormances of vanadium-based phosphates
2.1 Li3V2(PO4)3
2.2 LiVPO4F
2.3 (Li)VOPO4
2.4 LiVP2O7
3 Preparation methods of vanadium-based phosphates
3.1 High temperature solid state reaction
3.2 Carbothermal reduction
3.3 Sol-gel method
3.4 Microwave solid-state reaction
3.5 Hydrothermal process
3.6 Other methods
4 Strategies for the improvement of general performances
4.1 Coating or doping with high-conductivity materials
4.2 Doping with other ions
5 Conclusions and outlook

Key words: vanadium-based phosphate, lithium-ion batteries, cathode material

CLC Number: 

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