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Progress in Chemistry 2011, Vol. 23 Issue (9): 1936-1944 Previous Articles   Next Articles

• Review •

Progress of Preparation and Application of Cyclodextrin-based Molecular Tube

Zhang Lin1*, Li Linling1, Cheng Lihua2, Chen Huanlin1   

  1. 1. Engineering Research Center of Membrane and Water Treatment Technology, Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
    2. College of Environment and Resource Sciences, Zhejiang University, Hangzhou 310027, China
  • Received: Revised: Online: Published:
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Cyclodextrin-based molecular tube is a hollow tubular polymer synthesized by threaded cyclodextrins. Recently, it has received extensive attention since its tubular molecular structure and selective inclusion complexation characteristic with various guest molecules including small molecules and polymers. In this paper, the main properties of cyclodextrin-based molecular tube are introduced and the preparation methods are reviewed in detail and compared with each other. The research about the selective inclusion complexation between molecular tube and guest molecules is elaborated, which include long-chain aliphatic and aromatic compounds. The assembling mechanism and influencing factors of complexation are discussed later. The recent applications of molecular tube in self-assembled monolayers, artificial chaperone and potential applications in constructing of novel self-assembly supramolecular architecture are summarized. Finally, the future research directions and problems in this area are prospected.

Contents
1 Introduction
2 Preparation of cyclodextrin-based molecular tube
3 Inclusion complexation characteristic of cyclod-extrin-based molecular tube
3.1 α-CD Molecular tube's selective inclusion compl-exation with long-chain aliphatic compounds
3.2 α-CD Molecular tube's selective inclusion compl-exation with long-chain aromatic compounds
4 Studies on application of α-CD molecular tube
5 Mechanism and influencing factors of inclusion complexation between guest Molecular and α-CD molecular tube
6 Conclusions and outlook

Key words: cyclodextrin, molecular tube, inclusion complexation, self-assembly supramolecular architecture

CLC Number: 

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