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Progress in Chemistry 2011, Vol. 23 Issue (9): 1854-1861 Previous Articles   Next Articles

• Review •

Two-Photon Activable Photoacid Generators and Their Applications

Xia Rongjie, Jin Ming*, Wan Decheng, Pan Haiyan, Pu Hongting   

  1. Institute of Functional Polymers Materials, School of Materials Science & Engineering, Tongji University, Shanghai 201804, China
  • Received: Revised: Online: Published:
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Since 2000, the two-photon activable photoacid generators (PAGs) have attracted much attention and made some progress. There are two different ways for the application of two-photon in PAGs system. First is single molecular system, that is a PAG molecule which can decompose and generate strong acid under irradiation of laser by two-photon mode. Second one is a bi-molecular systems consisted of a photoacid generators and a sensitizer with high two-photon absorption cross section. The latter can transfer electron to PAG by intermolecular charge transfer. Both systems can efficiently initiate photopolymerization reactions by radical or cationic routes. In addition, the photoproduced protons can be used in 3D photolithography, 3D microfabrication. And finally, fine structures were prepared that can not accessiable by traditional linear one-photon mode. In this paper, the molecular structures of reported two-photon activable PAGs systems and their applications in two-photon 3D microfabrications are reviewed. It explores the photoacid generating mechnisms of different kinds of PAGs systems that can excitated by two-photon mode, and summarizes the present problems, that are mainly on the competitions between two-photon absorption cross sections and high quantum yield of photoacid generation, especially in single molecular systems. In the end, the future research direction in the development of two-photon activable PAGs systems are prospected.

Contents
1 Introduction
2 Progress of the two-photon activable photoacid generators (PAGs) systems
2.1 Single molecular two-photon activable PAGs systems
2.2 Bi-molecular two-photon activable PAGs systems
3 Applications of two-photon activable PAGs
4 Conclusion and perspectives

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