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Progress in Chemistry 2011, Vol. 23 Issue (7): 1372-1378 Previous Articles   Next Articles

• Special issues •

Synthesis and Crystal Structure of Uranyl Complexes

Liu Chunli*, Wang Luhua   

  1. Beijing National Laboratory for Molecular Sciences, Radiochemistry & Radiation Chemistry Key Laboratory for Fundamental Science, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
  • Received: Revised: Online: Published:
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Uranium is one of the most important nuclear materials. It is the core of the nuclear fuel cycle and the element to which much attention has been paid since it is inevitable that uranium is released in the process of uranium mining, enrichment, oxide fuel manufacturing and spent nuclear fuel reprocessing. Inorganic acid and carboxylic acid group of the humus can be coordinated to uranyl thus change its migration and sorption behavior in the environment. By analyzing the synthesis and crystal structure of uranyl complexes we can provide essential structure data for sorption modeling and sorption mechanism in the molecular level. The structural characters of uranyl primary building units and the complexes that may form with common inorganic and organic acids in the aquatic solutions have been reviewed. A proposal followed by the summary and analysis of the work carried out in the groups in the world of uranyl complexes based on environmentally concerned acids and some other oxo containing ligands is presented.

Key words: uranyl complexes, crystal structure, inorganic acids, peroxides, oxalic acid

CLC Number: 


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