中文
Earlier issues
Announcement
More
Progress in Chemistry 2011, Vol. 23 Issue (7): 1355-1365 Previous Articles   Next Articles

• Special issues •

Development of Silica-Based Supramolecular Recognition Materials in Reprocessing of Nuclear Spent Fuel

Zhang Anyun1,*, Xiao Chengliang1, Chai Zhifang1,2   

  1. 1. Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China;
    2. Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
  • Received: Revised: Online: Published:
PDF ( 1317 ) Cited
Export

EndNote

Ris

BibTeX

The new materials and new technologies are considered to play important roles in the advanced nuclear energy systems. Supramolecular recognition materials (SMRM) have received worldwide attention for several decades, and are becoming a hot research field in the spent nuclear fuel reprocessing. The research progress of the macroporous silica-based supramolecular recognition materials in spent fuel reprocessing are reviewed. The synthesis and characterization of silica-based supramolecular recognition materials and their respective adsorption properties for Cs(I)/Sr(Ⅱ) are summarized. The effects of various factors on the adsorption of the silica-based supramolecular recognition materials are evaluated. The SPEC process for strontium/cesium partitioning by extraction chromatography was discussed. It is found that the extraction chromatography processes based on the silica-based supramolecular recognition materials have following advantages: (1) high separation efficiency and excellent selectivity, (2) a minimal organic solvent utilization and less waste accumulation, (3) compacted equipment and simple operation, and (4) a real “salt-free” treatment, etc.

Contents
1 Introduction
2 Synthesis and characterization
2.1 Synthesis of silica-based SiO2-P support
2.2 Synthesis of silica-based supramolecular recognition materials
2.3 Characterization of silica-based supramolecular recognition materials
3 Development of silica-based materials in spent nuclear fuel reprocessing
3.1 Crown ether/SiO2-P
3.2 Calix[4]arene-crown-6/SiO2-P
3.3 Silica-basedsynergistic supramolecular recogni-tion materials
3.4 Other silica-based materials
4 Conclusions and outlooks

Key words: supramolecule recognition materials, silica-based support, heat generator, spent nuclear fuel, high level liquid waste

CLC Number: 


[1] Madic C. Overview of the Hydrome, tallurgical and Pyrometallurgical Processes Studied World-Wide for the Partitioning of High Active Nuclear Wastes. JAERI Conf., 2002-004, 27-37

[2] Dozol J F, Simon N, Lamare V, Rouquette H, Eymard S, Tournois B. Sep. Sci. Technol., 1999, 34: 877-909

[3] Tiwari D, Prasad S K, Yang J K, Choi B J, Lee S M. Environ. Eng. Res., 2006, 11: 106-125

[4] Simon N, Eymard S, Tournois B, Dozol J F. Caesium Extraction from Acidic High Level Liquid Waste with Functionalized Calixarenes. ATALANTE 2000, Avinon, France

[5] Walker D D, Norato M A, Campbell S G, Crowder M L, Fink S D, Fondeur F F, Geeting M W, Kessinger G F, Pierce R A. Sep. Sci. Technol., 2005, 40: 297-309

[6] Horwitz E P, Dietz M L, Fisher D E. Solvent Extr. Ion Exch., 1991, 9: 1-25

[7] Riddle C L, Baker J D, Law J D, McGrath C A, Meikrantz D H. Solvent Extr. Ion Exch., 2005, 23: 449-461

[8] 张安运(Zhang A Y), 柴之芳(Chai Z F). 先进核能化学中的新型多孔材料(Novel Macroporous Materials in Advanced Nuclear Energy Chemistry). 第15届全国分子筛学术大会(15th Chinese Zeolite Conference), 洛阳(Luoyang), 2010

[9] Zhang A Y, Wei Y Z, Kumagai, M. React. Funct. Polym., 2004, 61: 191-202

[10] Zhang A Y, Xiao C L, Hu Q H, Chai Z F. Solvent Extr. Ion Exch., 2010, 28: 526-542

[11] Zhang A Y, Hu Q H, Chai Z F. Sep. Sci. Technol., 2009, 44: 2146-2168

[12] Zhang A Y, Xiao C L, Liu Y H, Hu Q H, Chen C M, Kuraoka E. J. Porous Mater., 2010, 17: 153-161

[13] 肖成梁(Xiao C L). 浙江大学博士论文(Doctoral Dissertation of Zhejiang University), 2011

[14] Zhang A Y, Kuraoka E, Kumagai M. J. Chromatogr. A, 2007, 1157: 85-95

[15] Zhang A Y, Chen C M, Chai Z F, Kumagai M. Ads. Sci. Technol., 2008, 26: 705-720

[16] Zhang A Y, Xiao C L, Kuraoka E, Kumagai M. Ind. Eng. Chem. Res., 2007, 46: 2164-2171

[17] Zhang A Y, Xiao C L, Kuraoka E, Kumagai M. J. Hazard. Mater., 2007, 147: 601-609

[18] Zhang A Y, Chen C M, Wang W H, Wei Y Z. Solvent Extr. Ion Exch., 2008, 26: 624- 642

[19] Zhang A Y, Wang W H, Chai Z F, Kumagai M. J. Sep. Sci., 2008, 31: 3148-3155

[20] Zhang A Y, Xiao C L, Chai Z F. J. Radioanal. Nucl. Chem. 2009, 280: 181-191

[21] Zhang A Y, Wang W H, Chai Z F, Kuraoka E. Eur. Poly. J., 2008, 44: 3899-3907

[22] Zhang A Y, Chen C M, Kuraoka E, Kumagai, M. Sep. Purif. Technol., 2008, 62: 407-414

[23] Glennon J D, Horne E, Hall K, Cocker D, Kuhn A, Harris S J, McKervey M A. J. Chromatogr. A, 1996, 731: 47-55

[24] Arena G, Casnati A, Contino A, Mirone L, Sciotto D, Ungaro R. Chem. Commun., 1996, 19: 2277-2278

[25] Arena G, Contino A, Longo E, Sciotto D, Spoto G, Torrisi A. J. Supramol. Chem., 2002, 2: 521-531.

[26] Tavlarides L L, Lee J S, Nam K H, Agarwal N. Tsinghua Sci. Technol., 2006, 11: 233-240

[27] Zhang A Y, Wei Y Z, Hoshi H, Yoshikazu K. Solvent Extr. Ion Exch., 2007, 25: 389-405

[28] Zhang A Y, Xiao C L, Xue W J, Chai Z F. Sep. Purif. Technol., 2009, 66: 541-548

[29] Zhang A Y, Hu Q H, Chai Z F. AIChE J., 2010, 56: 2632-2640

[30] Zhang A Y, Hu Q H, Chai Z F. Ind. Eng. Chem. Res., 2010, 49: 2047-2054

[31] Zhang A Y, Hu Q H. Chem. Eng. J., 2010, 159: 58-66

[32] Xiao C L, Zhang A Y, Chai Z F. Solvent Extr. Ion Exch., 2011, 29(5), in press

[33] 张安运(Zhang A Y). CN 100460057C, 2009

[34] Zhang A Y, Kuraoka E, Kumagai M, Koma Y, Koyama T. J. Radioanal. Nucl. Chem., 2006, 269: 119-128

[35] Wei Y Z, Zhang A Y, Kumagai M, Watanabe M, Hayashi N. J. Nucl. Sci. Technol., 2004, 41: 315-322

[36] Zhang A Y, Hu Q H, Wang W H, Kuraoka E. Ind. Eng. Chem. Res., 2008, 47: 6158-6165

[37] Zhang A Y, Wei Y Z, Hoshi H, Kumagai M. Solvent Extr. Ion Exch., 2005, 23: 231-247

[38] Zhang A Y, Wei Y Z, Hoshi H, Kumagai M, Koma Y. Adsorpt. Sci. Technol., 2005, 23: 721-737

[39] Zhang A Y, Wei Y Z, Kumagai M. J. Radioanal. Nucl. Chem., 2005, 265: 409-417

[40] Zhang A Y, Etsusyo K, Hoshi H, Kumagai M. J. Chromatogr. A, 2004, 1061: 175-182

[41] Zhang A Y, Wei Y Z, Kumagai M, Koma Y, Koyama T. Radiat. Phy. Chem., 2005, 72: 455-463

[42] Zhang A Y, Wei Y Z, Kumagai M, Koma Y. J. Alloy Compd., 2005, 390: 275-281

[43] Zhang A Y, Kuraoka E, Kumagai M. Sep. Purif. Technol., 2007, 54: 363-372

[44] Zhang A Y, Kuraoka E, Kumagai M. J. Chromatogr. A, 2007, 1157: 85-95

[45] Zhang A Y, Wei Y Z, Kumagai M. Sep. Sci. Technol., 2007, 42: 2235-2253

[46] Zhang A Y, Chen C M, Wei Y Z, Kumagai M. Adsorpt. Sci. Technol., 2007, 25: 257-272

[47] Zhang A Y, Kuraoka E, Kumagai M. Sep. Purif. Technol., 2006, 50: 35-44

[48] Zhang A Y, Wei Y Z, Hoshi H, Kumagai M. Sep. Sci. Technol., 2005, 40: 811-827

[49] Zhang A Y, Wei Y Z, Hoshi H, Kumagai M, Kamiya M, Koyama T. Radiat. Phy. Chem., 2005, 72: 669-678

[50] Kolarik Z, Mullich U, Gassner F. Solvent Extr. Ion Exch., 1999, 17: 1155-1170

[51] Hill C, Guilianeux D, Berthon L, Madic C. SANEX-BTP Process Development Studies. JAERI-Conf., 2002-004, 573-578

[52] Magnusson D, Christiasen B, Forman M R S, Geist A, Glatz J P, Malmbeck R, Modolo G, Serrano-Purroy D, Sorel C. Solvent Extr. Ion Exch., 2009, 27: 97-106

[53] Zhang A Y, Kuraoka E, Kumagai M. J. Radioanal. Nucl. Chem., 2007, 274: 455-464

[54] Wei Y Z, Hoshi H, Kumagai M, Asakura T, Morita Y. J. Alloy Compd., 2004, 374: 447-450

[55] Hoshi H, Wei Y Z, Kumagai M, Asakura T, Morita Y. J. Alloy Compd., 2006, 408/412: 1274-1277

[56] Zhang A Y, Wang X Y, Chai Z F. AIChE J., 2010, 56: 3074-3083

[57] Zhang A Y, Zhu Y P, Liu Y H, Chai Z F. Ind. Eng. Chem. Res., 2011, 50, in press
[1] Yaoyang Liu, Zhibin Liu, Chuang Zhao, Yu Zhou, Yang Gao, Hui He. Separation of Actinides: Extraction Chemistry and Application of Unsymmetric Diglycolamides [J]. Progress in Chemistry, 2020, 32(2/3): 219-229.
[2] Wei Yuezhou. Progress and Discussion on Chemical Separation Technologies for Nuclear Fuel Reprocessing Abroad [J]. Progress in Chemistry, 2011, 23(7): 1272-1288.
[3] Zhu Liyang, Wen Mingfen, Duan Wuhua, Xu Jingming, Zhu Yongjun. Application of Supercritical Fluid Extraction in Reprocessing of Spent Nuclear Fuel [J]. Progress in Chemistry, 2011, 23(7): 1308-1315.
[4] Chen Jing, Wang Jianchen. Overview of 30 Years Research on TRPO Process for Actinides Partitioning from High Level Liquid Waste [J]. Progress in Chemistry, 2011, 23(7): 1366-1371.
[5] Daqing Cui. A Review of Beneficial Effects of Ruducing Environment at the Near-field of KBS-3 Repository [J]. Progress in Chemistry, 2011, 23(7): 1411-1428.