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Progress in Chemistry 2011, Vol. 23 Issue (7): 1345-1354 Previous Articles   Next Articles

• Special issues •

Calixarene Derivatives for An(Ⅲ)/Ln(Ⅲ) Separation in Nuclear Fuel Reprocessing

Yang Yanqiu*, Luo Shunzhong, Yang Tongzai, Hao Fanhua   

  1. Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, China
  • Received: Revised: Online: Published:
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In the process of partitioning HLW, an urgent subject is focus on the development of extraction ligands for actinides (An(Ⅲ)) over lanthanides (Ln(Ⅲ)) with excellent selectivity. It is well known that the preorganization of ligands considerably improves their extraction capacity and selectivity to certain cations. Calixarenes offer ideal platforms to such preorganization.From the 1990s on, large amounts of calixarene derivatives bearing various complexation functionalites to An(Ⅲ) have been synthesized. Many of them showed improved extraction properties and higher extraction selectivity to An(Ⅲ). In this review, the An(Ⅲ)/Ln(Ⅲ) extraction properties of various calixarene derivatives bearing ligands, such as carbamoylmentylphosphine oxide, dialkylphosphine oxide, picolinamide, and other function moities, were summarized at large. Emphasis was placed on the relationship of the structures of the calixarene derivatives to the preorganization of ligands, the extraction properties and the separation factor of An(Ⅲ)/Ln(Ⅲ). The developing directions and the potential application of such derivatives for An(Ⅲ)/Ln(Ⅲ) separation were described.

Contents
1 Introduction
2 Effect of the Preorganization of Ligands on the Extraction Properties
3 The Extraction Properties of Calixarene Derivatives Bearing CMPO Moieties
3.1 Upper rim CMPO Calixrenes
3.2 Lower rim CMPO Calixrenes
3.3 CMPO Adamantyl Calixarenes
3.4 Other Calixarene-CMPO Derivatives
4 The Extraction Properties of Phosphine Oxide Derivatives of Calixarenes
5 The Extraction Properties of Picolinamide Derivatives of Calixarenes
6 Summary and outlook

Key words: partition and transmutation, minor actinide elements, lanthanide elements, extractant, calixarene derivatives, phosphine oxide, picolinamide

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