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Progress in Chemistry 2011, Vol. 23 Issue (6): 1181-1188 Previous Articles   Next Articles

• Review •

Nonisocyanate Polyurethanes and Their Applications

Huang Yaocheng1, Liang Liyun1, Ren Xu2, Tan Bien1*   

  1. 1. Hubei Key Laboratory of Materials Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China;
    2. Shenzhen Tianxudong Keji Co., Ltd, Shenzhen 518172, China
  • Received: Revised: Online: Published:
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Polyurethane (PU) is one of the most important polymer materials due to its excellent properties, such as durability, impact resistance, stress relaxation, tear resistance and adhesion. However, isocyanate, which is a key monomer for conventional PU, has some drawbacks such as high toxicity and sensitivity to moisture. Also, urethane group is poorly resistant to hydrolysis.The reaction between cyclic carbonates and primary amines is a promising nonisocyanate route to produce PU. Nonisocyanate polyurethanes (NIPUs) produced by this method are more resistant to hydrolysis and have better mechanical properties due to the formation of intramolecular hydrogen bonds within the hydrourethane groups. In this paper, the formation mechanism of NIPUs is introduced. The synthesis methods of cyclic carbonate group and its catalyst systems are summarized. The progress of synthesis of cyclic carbonate oligomers and NIPUs as well as their applications are reviewed. Also, the reasons why NIPUs have not yet been widely commercially available and the research prospects are discussed.

Key words: cyclic carbonate, nonisocyanate polyurethanes, synthesis, application

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