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Progress in Chemistry 2011, Vol. 23 Issue (6): 1137-1147 Previous Articles   Next Articles

• Review •

Recent Advances in Silver-Mediated Organic Synthesis Reactions

Liu Guannan1,2, Zhou Yu1, Jiang Hualiang1, Liu Hong1*   

  1. 1. Drug Discovery and Design Centre, State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, China;
    2. China Jiliang University, College of Life Sciences, Hangzhou 310018, China
  • Received: Revised: Online: Published:
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The silver-catalyzed reaction is one of the frontier areas in organic chemistry, and the progress of research on it was rapid. In comparison with other transition metal salts, Ag(Ⅰ) have long been believed to have low catalytic efficiency, and most commonly served as either co-catalysts or Lewis acids. Only recently, Ag(I) have been demonstrated to be important and versatile catalysts for a variety of organic transformations. Ag(Ⅰ) is known to activate π-systems, such as alkenes, alkynes, and allenes, towards intermolecular and intramolecular nucleophilic attack. Moreover, efforts in studying silver-catalyzed organic transformations have focused on coupling reactions and asymmetric reactions. In addition, the use of silver(I) is economic relative to other expensive transition metals. Recent development of silver(I)-catalyzed reactions is reviewed, whose substrates, reaction conditions, selectivity, yields and mechanisms have been discussed and summarized.

Key words: Ag-mediated, synthesis of heterocycles, coupling reaction, asymmetric reaction

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