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Progress in Chemistry 2011, Vol. 23 Issue (6): 1050-1059 Previous Articles   Next Articles

• Invited Article •

Substituted Vanadium-Oxide Clusters

Gao Yuanzhe1,2, Hu Changwen1*, Li Xiaofang1*   

  1. 1. Key Laboratory of Cluster Science, Ministry of Education, Beijing Institute of Technology, Beijing 100081, China;
    2. College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050016, China
  • Received: Revised: Online: Published:
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Vanadium-oxide clusters are one class of the most important polyoxometalates. The design and assembly of polyoxovanadates (POVs) are currently of great interest in the field of crystal engineering, not only because of their structural diversity, but also their potential applications in the fields of catalytic, magnetic and optical materials. To date, a brand-new class of POVs with the incorporation of main group elements into vanadium-oxide clusters has been widely investigated. In recent years, transition-metal complexes (TMCs) are utilized to combine with different substituted vanadium-oxide clusters for the construction of various novel structural types with desired properties, which not only greatly enriched the structure of vanadium-oxide clusters, but also promoted its continuous development in the synthesis. A review has been mainly given to the new development of the substituted vanadium-oxide clusters in the aspects of structural characteristics and magnetic properties over the past several years. The prospects of them are also discussed in this paper.

Key words: substituted vanadium-oxide clusters, synthesis, structures, magnetic properties

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Abstract

Substituted Vanadium-Oxide Clusters