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Progress in Chemistry 2011, Vol. 23 Issue (5): 941-950 Previous Articles   Next Articles

• Review •

Surface Modification and Application of Quantum Dots Based on Polymers

Lai Shoujun, Guan Xiaolin   

  1. Department of Chemistry & Environmental Engineering, Chongqing Three Gorges University, Chongqing 404000, China
  • Received: Revised: Online: Published:
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Quantum dots (QDs) are nanometer-sized structures with the remarkable optical characteration, which have widely used in biology, chemistry and physics. Polymeric materials are not only employed as matrices for QDs for optical applications, but also provide mechanical and chemical stability to QDs as well as preventing nanocrystal agglomeration, and offering processability into technologically relevant structures. Using polymers as the modifier of QDs, surface modifications are especially required to permit monodispersion of materials, and further functionalization is necessary to facilitate specific biological and chemical interactions. The present review summarizes recent research in the development of polymer-modified QDs materials, their synthesis and fabrication methods, as well as resulting optical properties and applications. It is briefly described on surface coating of QDs with amphiphilic polymers, multivalent polymerization of QDs surface, synthesis of end-functionalized polymers on the QDs surface and preparation of the dendrimer-quantum dots materials. Surface coating of QDs with amphiphilic polymers would improve water solubility and chemical functionality of the materials. Multidentate polymeric ligands have the ability to retain the luminescence quantum yields, and to simultaneously provide the necessary colloidal stability with chemical functionality. Attachment of end-functionalized polymers to the QDs surface lead to many new applications for such advanced materials. In addition, dendrimer-encapsulated approaches have been used for the controlled synthesis of QDs. Moreover, the perspective and application about the modification are also reviewed.

Key words: quantum dots, polymers, modification Contents

CLC Number: 

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