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• Review •

Capture of CO2 by Ionic Liquids

Zhou Lingyun1,2, Fan Jing1, Wang Jianji1   

  1. 1. School of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007, China;
    2. College of Resource and Environment, Henan Institute of Science and Technology, Xinxiang 453003, China
  • Received: Revised: Online: Published:
  • Contact: Wang Jianji E-mail:jwang@henannu.edu.cn
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Since CO2 is one of the most important greenhouse gases, the research and development in the carbon capture have long been the focus of many academic and industrial studies. Ionic liquids have a number of unique properties, such as no-volatility, non-flammation, recyclability, high thermal stability, strong solubility capacity, and the tunability of molecular structures and physicochemical properties. Thus they have promising application in absorption and separation of CO2. In this paper, the recent progress in the CO2 capture by using regular ionic liquids, task-specific ionic liquids, supported ionic-liquids membranes, polymerized ionic liquids and the mixtures of ionic liquids with some molecular solvents have been reviewed. The effects of cationic structure, anionic property, alkyl chain length, functionalization of both the cations and the anions, characteristics of the supported membranes, the polymerized degree of ionic liquids, temperature and pressure of the systems on the selective capture of CO2 are discussed in detail. The possible mechanisms for the capture and selective separation of CO2 are also demonstrated. Furthermore, the advantages and disadvantages have been analyzed for the above mentioned ionic liquids systems in the capture of CO2. The future development in this area is prospected, and several important issues are suggested for the further work.

Contents
1 Introduction
2 CO2 capture by ionic liquids
2.1 Regular ionic liquids
2.2 Task-specific ionic liquids
2.3 Supported ionic liquid membranes
2.4 Polymerized ionic liquids
2.5 Mixtures of ionic liquids with molecular solvents
3 Conclusions and outlook

Key words: ionic liquids, CO2 capture, absorption, separation

CLC Number: 

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Abstract

Capture of CO2 by Ionic Liquids