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• Review •

Gas Separation Based on Ionic Liquids

Zhao Xu, Xing Huabin, Li Rulong, Yang Qiwei, Su Baogen, Ren Qilong   

  1. National Laboratory of Secondary Resources Chemical Engineering, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
  • Received: Revised: Online: Published:
  • Contact: Xing Huabin E-mail:xinghb@zju.edu.cn
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In recent years, ionic liquids have attracted considerable interests in the field of gas separation, due to their selective dissolution of certain gases, nearly non-volatility and tunable property and structure. In this article, the solubilities of CO2, SO2, H2, O2, CO, N2, Ar, Xe and short-chain alkanes, alkenes, alkynes in ionic liquids are summarized. The mechanism and the qualitative relationship between gas solubility and the structure of ionic liquid are introduced. Functionalized ionic liquids containing basic groups such as amino and guanidine have high performance to capture CO2 and SO2. The solubilities of alkenes in ionic liquids can be improved by adding unsaturated groups in ionic liquids via π-π interaction, and the solubility of alkynes in ionic liquids increases with increasing hydrogen-bond basicity of ionic liquids. The progress involving molecular simulation of ionic liquid/gas binary system, correlation models of gas solubility, and gas separation based on immobilized ionic liquids are introduced and summarized. Finally, the existing problems and development directions in the future of gas separation using ionic liquids are discussed.

Contents
1 Introduction
2 Solubilities of gases in ionic liquids
2.1 Acidic gases
2.2 Organic gases
2.3 Other gases
3 Molecular simulation study of ionic liquid/gas mixture
4 Correlation models of gas solubility in ionic liquids
5 Gas separation based on immobilized ionic liquids
6 Conclusions and outlook

Key words: ionic liquid, gas, solubility, separation, absorption

CLC Number: 

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Abstract

Gas Separation Based on Ionic Liquids