中文
Earlier issues
Announcement
More
Progress in Chemistry Previous Articles   Next Articles

• Review •

Preparation Methods of Ruthenium Catalysts for Ammonia Synthesis

Zhang Liuming, Lin Jianxin, Ni Jun, Lin Bingyu, Wang Rong, Wei Kemei   

  1. National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China
  • Received: Revised: Online: Published:
  • Contact: Lin Jianxin E-mail:lin3jx@fzu.edu.cn
PDF ( 1837 ) Cited
Export

EndNote

Ris

BibTeX

The ruthenium catalysts for ammonia synthesis have higher activity than the iron catalyst, especially under the condition of low temperature and pressure. Different preparation methods and preparation conditions will influence the ruthenium catalyst activity with different support materials. This paper describes the preparation methods of Ru catalysts for ammonia synthesis from three aspects, including the pretreatment of supports, the loading of Ru and the addition of promoters. Different methods such as melting method, sublimation method, ion exchange, ultrasound method, precipitation, sol-gel method, impregnate method, microwave-assisted method are reviewed and the shortages of some methods are discussed. The development trends of the preparation of Ru catalyst are also proposed.

Contents
1 Introduction
2 Pretreatment of supports
2.1 Heat treatment
2.2 Oxidation treatment
2.3 Other treatment methods
3 Preparation methods of ruthenium catalysts and promoters
3.1 Melting method
3.2 Sublimation method
3.3 Ion exchange method
3.4 Sol-gel method
3.5 Microwave-assisted synthesis
3.6 Ultrasound-assisted synthesis
3.7 Precipitation method
3.8 Impregnation method
4 Conclusions and outlook

Key words: ruthenium, ammonia synthesis, catalysts, preparation methods

CLC Number: 

[1] 郑晓玲(Zheng X L), 魏可镁(Wei K M). 化学进展(Progress in Chemistry), 2001, 13: 472-480
[2] Niwa Y, Aika K. J. Catal., 1996, 162: 138-142
[3] Dahl S, Logadottir A, Egeberg R C, Larsen J H, Chorkendorff I, Tornqvist E, Norskov J K. Phys. Rev. Lett., 1999, 83: 1814-1817
[4] Dahl S, Taylor P A, Tornqvist E, Chorkendorff E. J. Catal., 1998, 178: 679-686
[5] Dahl S, Tornqvist E, Chorkendorff I. J. Catal., 2000, 192: 381-390
[6] Van Hardeveld R, van Montfoort A. Surf. Sci., 1966, 4: 396-430
[7] Rarog-Pilecka W, Miskiewicz E, Szmigiel D, Kowalczyk Z. J. Catal., 2005, 231: 11-19
[8] Kowalczyk Z, Szmigiel D, Rarog-Pilecka W, Komornicki A, Kielak M, Glinski M. Przem. Chem., 2003, 82: 725-727
[9] Xu Q, Lin J, Li J, Fu X, Liang Y, Liao D. Catal. Commun., 2007, 8: 1881-1885
[10] Ni J, Wang R, Lin J X, Wei K M. Acta Phys. Chim. Sin., 2009, 25: 519-524
[11] Wang R, Wei K, Lin J X, Yu X J, Mao S L. Chin. J. Catal., 2003, 24: 929-932
[12] Kowalczyk Z, Sentek J, Jodzis S, Diduszko R, Presz A, Terzyk A, Kucharski Z, Suwalski J. Carbon, 1996, 34: 403-409
[13] Kowalczyk Z, Sentek J, Jodzis S, Mizera E, Góralski J, Paryjczak T, Diduszko R. Cata. Lett., 1997, 45: 65-72
[14] Forni L, Molinari D, Rossetti I, Pernicone N. Appl. Catal. A, 1999, 185: 269-275
[15] Zhong Z H, Aika K. J. Catal., 1998, 173: 535-539
[16] Zhong Z H, Aika K. Chem. Commun., 1997, 1223-1224
[17] Tang T D, Yin C Y, Xiao N, Guo M Y, Xiao F S. Catal. Lett., 2009, 127: 400-405
[18] 林建新(Lin J X), 郑勇(Zheng Y), 郑瑛(Zheng Y), 魏可镁(Wei K M). 无机化学学报(Chinese Journal of Inorganic Chemistry), 2006, 22(10): 1778-1782
[19] 郑瑛(Zheng Y), 郑勇(Zheng Y), 林良旭(Lin L X), 魏可镁(Wei K M). 功能材料(Journal of Functional Materials), 2006, 12: 1948-1950
[20] 郑勇(Zheng Y), 郑瑛(Zheng Y), 于伟鹏(Yu W P), 王榕(Wang R), 魏可镁(Wei K M). 无机化学学报(Chinese Journal of Inorganic Chemistry), 2008, 24(6): 1001-1007
[21] 于伟鹏(Yu W P). 福建师范大学硕士论文(Master Dissertation of Fujian Normal University), 2009
[22] Zheng Y, Li Z H, Yu H Y, Wang R, Wei K M. J. Mol. Catal. A: Chem., 2009, 301: 79-83
[23] 林炳裕(Lin B Y), 林建新(Lin J X), 倪军(Ni J), 王榕(Wang R), 魏可镁(Wei K M). 第十四届全国催化会议论文集(The 14th National Academic Conference of Catalysis). 南京(Nanjing), 2008. 160
[24] Xu C F, Ouyang L A, Zhang J, Zhou B, Li Y, Liu H Z. Chin. J. Catal., 2010, 31: 677-682
[25] Jacobsen C J H. J. Catal., 2001, 200: 1-3
[26] Szmigiel D, Raróg-Pilecka W, Mi Ds＇ kiewicz E, Maciejewska E, Kaszkur Z, Sobczak J W, Kowalczyk Z. Catal. Lett., 2005, 100: 79-87
[27] Becue T, Davis R J, Garces J M. J. Catal., 1998, 179: 129-137
[28] Cisneros M D, Lunsford J H. J. Catal., 1993, 141: 191-205
[29] Fishel C T, Davis R J, Garces J M. Chem. Commun., 1996, 649-650
[30] Fishel C T, Davis C T, Garces J M. J. Catal., 1996, 163: 148-157
[31] Wellenbuscher J, Muhler M, Mahdi W, Sauerlandt U, Schutze J, Ertl G, Schlogl R. Catal. Lett., 1994, 25: 61-74
[32] Wellenbüuscher J, Rosowski F, Klengler U, Muhler M, Ertl G, Guntow U, Schlogl R. The Application of Ru-Exchanged Zeolite NaY in Ammonia Synthesis(Eds. Weitkamp J, Karge H G, Pfeifer H, Hlderich W). Berlin: Elsevier, 1994. 941-948
[33] Guntow U, Rosowski F, Muhler M, Ertl G, Schlogl R. The Preparation of Stable Ru Metal Clusters in Zeolite Y Used As Catalyst for Ammonia Synthesis(Eds. Poncelet G, Martens J, Delmon B, Jacobs P A, Grange P). Berlin: Elsevier, 1995. 217-226
[34] Huo C, Zhang X H, Xia Q H, Yang X Z, Luo Y, Liu H Z. Chin. J. Catal., 2010, 31: 360-364
[35] Luo X J, Wang R, Ni J, Lin J X, Lin B Y, Xu X M, Wei K M. Catal. Lett., 2009, 133: 382-387
[36] Saito M, Itoh M, Iwamoto J, Li C Y, Machida K. Catal. Lett., 2006, 106: 107-110
[37] Wang X, Ni J, Lin B, Wang R, Lin J, Wei K. Catal. Commun., 2010, 12: 251-254
[38] Kowalczyk Z, Jodzis S, Rarog W, Zielinski J, Pielaszek J. Appl. Catal. A, 1998, 173: 153-160
[39] Kowalczyk Z, Jodzis S, Rarog W, Zielinski J, Pielaszek J, Presz A. Appl. Catal. A, 1999, 184: 95-102
[40] 郑晓玲(Zheng X L), 张淑娟(Zhang S J), 魏可镁(Wei K M). 燃料化学学报(Journal of Fuel Chemistry and Technology), 2001, 29: 96-99
[41] Rossetti I, Pernicone N, Forni L. Appl. Catal. A, 2001, 208: 271-278
[42] Zheng X L, Zhang S J, Lin J X, Xu J X, Fu W J, Wei K M. Chem. Res. Chin. Univ., 2002, 18: 448-452
[43] 朱虹(Zhu H), 韩文锋(Han W F), 柴海芳(Chai H F), 刘化章(Liu H Z). 催化学报(Chinese Journal of Catalysis), 2007, 28(3): 196-200
[44] Zhong Z H, Aika K. Inorg. Chim. Acta, 1998, 280: 183-188
[45] Rossetti I, Pernicone N, Forni L. Catal. Today, 2005, 102-103: 219-224
[46] McCarroll J J, Tennison S R, Wilkinson N P. US 4600571, 1986
[47] Gereld K T X, Benner S, Joseph H T X, Le R B, Jing S T X, Lee M, Harry H T X, Leftin P, Philip K T X, Shires J, Christiaan H T X, van Dijk P. US 06661482, 1986
[48] 王榕(Wang R), 魏可镁(Wei K M), 俞秀金(Yu X J), 林建新(Lin J X), 毛树禄(Mao S L). CN 1544146, 2004
[49] 张新波(Zhang X B), 李小年(Li X N), 霍超(Huo C), 岑亚青(Cen Y Q), 祝一锋(Zhu Y F), 刘化章(Liu H Z). 催化学报(Chinese Journal of Catalysis), 2002, 23: 207-213
[50] 王榕(Wang R), 魏可镁(Wei K M), 林建新(Lin J X), 俞秀金(Yu X J), 毛树禄(Mao S L). 工业催化(Industrial Catalysis), 2005, 13(4): 32-35
[51] Rodriguez-Reinoso F. Carbon, 1998, 36: 159-175
[52] Lyubchik S B, Benoit R, Béguin F. Carbon, 2002, 40: 1287-1294
[53] Pradhan B K, Sandle N K. Carbon, 1999, 37: 1323-1332
[54] El-Hendawy A N A. Carbon, 2003, 41: 713-722
[55] 韩文锋(Han W F), 赵波(Zhao B), 霍超(Huo C), 刘化章(Liu H Z). 催化学报(Chinese Journal of Catalysis), 2004, 25: 194-198
[56] 毛树禄(Mao S L). 福州大学硕士论文(Master Dissertation of Fuzhou University), 2004
[57] Yu X J, Lin B Y, Gong B B, Lin J X, Wang R, Wei K M. Catal. Lett., 2008, 124: 168-173
[58] 王建梅(Wang J M), 王榕(Wang R), 林建新(Lin J X), 俞秀金(Yu X J),谢峰(Xie F), 魏可镁(Wei K M). 福州大学学报(自然科学版)(Journal of Fuzhou University(Natural Science Edition)), 2006, 34: 898-902
[59] Yu F W, Ji J B, Xu Z C, Liu H Z. Ultrasonics, 2006, 44: 389-392
[60] 于凤文(Yui F W), 计建炳(Ji J B), 霍超(Huo C), 韩文锋(Han W F), 李小年(Li X N), 刘化章(Liu H Z). 催化学报(Chinese Journal of Catalysis), 2006, 27: 511-514
[61] 霍超(Huo C), 于凤文(Yu F W), 范青明(Fan Q M), 郑遗凡(Zheng Y F), 刘化章(Liu H Z). 化学反应工程与工艺(Chemical Reaction Engineering and Technology), 2007, 23: 263-266
[62] 郑晓玲(Zheng X L), 傅武俊(Fu W J), 俞裕斌(Yu Y B), 林建新(Lin J X), 魏可镁(Wei K M). 催化学报(Chinese Journal of Catalysis), 2002, 23: 562-566
[63] Song Z, Cai T H, Hanson J C, Rodriguez J A, Hrbek J. J. Am. Chem. Soc., 2004, 126: 8576-8584
[64] Bielawa H, Hinrichsen O, Birkner A, Muhler M. Angewandte Chemie-International Edition, 2001, 40: 1061-1063
[65] McClaine B C, Siporin S E, Davis R J. J. Phys. Chem. B, 2001, 105: 7525-7532
[66] Mahdi W, Sauerlandt U, Wellenbüscher J, Schütze J, Muhler M, Ertl G, Schlgl R. Catal. Lett., 1992, 14: 339-348
[67] Siporin S E, McClaine B C, Anderson S L, Davis R J. Catal. Lett., 2002, 81: 265-269
[68] Xu Q, Lin J, Fu X, Liao D. Catal. Commun., 2008, 9: 1214-1218
[69] Wu S, Chen J X, Zheng X F, Zeng H S, Zheng C M, Guan N J. Chem. Commun., 2003, 2488-2489
[70] Ni J, Wang R, Lin J, Wei K. Catal. Lett., 2008, 126: 134-141
[71] 倪军(Ni J), 王榕(Wang R), 林建新(Lin J X), 魏可镁(Wei K M). 物理化学学报(Acta Physico-Chimica Sinica), 2009, 25(3): 519-524
[72] Moggi P, Predieri G, Maione A. Catal. Lett., 2002, 79: 7-15
[73] Chen W X, Lee J Y, Liu Z. Mater. Lett., 2004, 58: 3166-3169
[74] 杨伯伦(Yang B L), 贺拥军(He Y J). 现代化工(Modern Chemical Industry Monthly), 2001, 21: 8-12
[75] 程敬泉(Cheng J Q), 姚素薇(Yao S W). 电镀与精饰(Plating & Finishing), 2005, 27: 16-20
[76] 霍超(Huo C), 夏庆华(Xia Q H), 杨霞珍(Yang X Z), 骆燕(Luo Y), 刘化章(Liu H Z). 催化学报(Chinese Journal of Catalysis), 2009, 30: 218-221
[77] 霍超(Huo C), 夏庆华(Xia Q H), 杨霞珍(Yang X Z), 骆燕(Luo Y), 刘化章(Liu H Z). 催化学报(Chinese Journal of Catalysis), 2009, 30: 537-542
[78] 霍超(Huo C), 晏刚(Yan G), 郑遗凡(Zheng Y F), 于凤文(Yu F W), 刘化章(Liu H Z). 催化学报(Chinese Journal of Catalysis), 2007, 28: 484-488
[79] 霍超(Huo C), 张学辉(Zhang X H), 夏庆华(Xia Q H), 杨霞珍(Yang X Z), 骆燕(Luo Y), 刘化章(Liu H Z). 催化学报(Chinese Journal of Catalysis), 2010, 31: 360-364
[80] Bedrane S, Descorme C, Duprez D. J. Mater. Chem., 2002, 12: 1563-1567
[81] Luo X J, Wang R, Ni J, Lin J X, Wei K M. Acta Chim. Sinica, 2009, 67: 2573-2578
[82] 罗小军(Luo X J), 王榕(Wang R), 林建新(Lin J X), 魏可镁(Wei K M). 催化学报(Chinese Journal of Catalysis), 2009, 30: 1125-1130
[83] 王晓南(Wang X N), 朱虹(Zhu H), 夏伟琴(Xia W Q), 刘化章(Liu H Z). 催化学报(Chinese Journal of Catalysis), 2000, 21: 276-278
[84] 郑晓玲(Zheng X L), 傅武俊(Fu W J), 俞裕斌(Yu Y B), 张淑娟(Zhang S J), 许交兴(Xu J X), 魏可镁(Wei K M). 燃料化学学报(Journal of Fuel Chemistry and Technology), 2003, 31: 86-91
[85] 赵波(Zhao B). 浙江工业大学硕士论文(Master Dissertation of Zhejiang University of Technology), 2004
[86] 许清池(Xu Q C). 厦门大学博士论文(Doctoral Dissertation of Xiamen University), 2008
[87] 荣成(Rong C), 王榕(Wang R), 郑超(Zheng C), 魏可镁(Wei K M). 福州大学学报(自然科学版)(Journal of Fuzhou University(Natural Science Edition)), 2006, 34(1): 133-136
[88] 王榕(Wang R), 魏可镁(Wei K M), 林建新(Lin J X), 俞秀金(Yu X J), 倪军(Ni J), 林炳裕(Lin B Y), 瞿胜(Qu S), 谢峰(Xie F), 莫崇望(Mo C W). CN 101362080, 2009
[1] Jiaye Li, Peng Zhang, Yuan Pan. Single-Atom Catalysts for Electrocatalytic Carbon Dioxide Reduction at High Current Densities [J]. Progress in Chemistry, 2023, 35(4): 643-654.
[2] Yuewen Shao, Qingyang Li, Xinyi Dong, Mengjiao Fan, Lijun Zhang, Xun Hu. Heterogeneous Bifunctional Catalysts for Catalyzing Conversion of Levulinic Acid to γ-Valerolactone [J]. Progress in Chemistry, 2023, 35(4): 593-605.
[3] Chunyi Ye, Yang Yang, Xuexian Wu, Ping Ding, Jingli Luo, Xianzhu Fu. Preparation and Application of Palladium-Copper Nano Electrocatalysts [J]. Progress in Chemistry, 2022, 34(9): 1896-1910.
[4] Mingjue Zhang, Changpo Fan, Long Wang, Xuejing Wu, Yu Zhou, Jun Wang. Catalytic Reaction Mechanism for Hydroxylation of Benzene to Phenol with H2O2/O2 as Oxidants [J]. Progress in Chemistry, 2022, 34(5): 1026-1041.
[5] Shujin Shen, Cheng Han, Bing Wang, Yingde Wang. Transition Metal Single-Atom Electrocatalysts for CO2 Reduction to CO [J]. Progress in Chemistry, 2022, 34(3): 533-546.
[6] Yang Linyan, Guo Yupeng, Li Zhengjia, Cen Jie, Yao Nan, Li Xiaonian. Modulation of Surface and Interface Properties of Cobalt-Based Fischer-Tropsch Synthesis Catalyst [J]. Progress in Chemistry, 2022, 34(10): 2254-2266.
[7] Wu Qiaomei, Yang Qiyue, Zeng Xianhai, Deng Jiahui, Zhang Liangqing, Qiu Jiarong. Catalytic Conversion of Cellulose-Based Biomass to Diols [J]. Progress in Chemistry, 2022, 34(10): 2173-2189.
[8] Yuan Su, Keming Ji, Jiayao Xun, Liang Zhao, Kan Zhang, Ping Liu. Catalysts for Catalytic Oxidation of Formaldehyde and Reaction Mechanism [J]. Progress in Chemistry, 2021, 33(9): 1560-1570.
[9] Xiangchun Tang, Jiaxiang Chen, Lina Liu, Shijun Liao. Pt-Based Electrocatalysts with Special Three-Dimensional Morphology or Nanostructure [J]. Progress in Chemistry, 2021, 33(7): 1238-1248.
[10] Xiaolu Liu, Yuxiao Geng, Ran Hao, Yuping Liu, Zhongyong Yuan, Wei Li. Electrocatalytic Nitrogen Reduction Reaction under Ambient Condition: Current Status, Challenges, and Perspectives [J]. Progress in Chemistry, 2021, 33(7): 1074-1091.
[11] Jingchen Tian, Gongde Wu, Yanjun Liu, Jie Wan, Xiaoli Wang, Lin Deng. Application of Supported Non-Noble Metal Catalysts for Formaldehyde Oxidation at Low Temperature [J]. Progress in Chemistry, 2021, 33(11): 2069-2084.
[12] Yiqiang Liu, Yimei Qiu, Xing Tang, Yong Sun, Xianhai Zeng, Lu Lin. Glucose Isomerization into Fructose by Chemocatalytic Route [J]. Progress in Chemistry, 2021, 33(11): 2128-2137.
[13] Andong Hu, Shungui Zhou, Jie Ye. The Mechanism, Progress and Prospect of Biohybrid Mediated Semi-Artificial Photosynthesis [J]. Progress in Chemistry, 2021, 33(11): 2103-2115.
[14] Mengting Xu, Yanqing Wang, Ya Mao, Jingjuan Li, Zhidong Jiang, Xianxia Yuan. Cathode Catalysts for Non-Aqueous Lithium-Air Batteries [J]. Progress in Chemistry, 2021, 33(10): 1679-1692.
[15] Weiyang Lv, Ji’an Sun, Yuyuan Yao, Miao Du, Qiang Zheng. Morphology Control of Layered Double Hydroxide and Its Application in Water Remediation [J]. Progress in Chemistry, 2020, 32(12): 2049-2063.