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Progress in Chemistry 2011, Vol. 23 Issue (11): 2183-2199 Previous Articles   Next Articles

• Invited Article •

Functional Inorganic-Cellulose Hybrid Nanocomposites

Xu Yan   

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China
  • Received: Online: Published:
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This paper provides an overview of the recent progress made in the area of functional inorganic-cellulose hybrid nanocomposites. The new advances reviewed are the use of nanocrystalline cellulose (NCC) as matrix materials to enhance the functionality of inorganic materials, as a biotemplating agent to generate nanocomposites with a hierarchical structure for improved functionality and the use of inorganic nanoparticles to generate functional inorganic-cellulose hybrid nanocomposites. An introduction into the methods used to assemble inorganic-cellulose hybrid nanocomposites is given with special attention to electrospinning method, templated mineralization via the structural feature, H-bonds network and the biosynthesis route of cellulose, sol-gel method, solution-casting method and layer-by-layer method. The types of NCC covered include those extracted from higher plants, tunicates and bacteria cellulose (BC). An introduction into NCC covering general aspects of their preparation, crystal structures and morphology, arrangement and orientation under different conditions, chemical modification and solvents is made. Lignocellulose and sea cucumber dermis are fiber nanocomposites with a hierarchical structure. Their exceptional mechanical properties and intelligence are believed to be due to a functional adaptation of the structure at all levels of hierarchy. Selected bio-inspired cellulose nanocomposites are discussed to manifest how the hierarchical and helical feature of NCC can be used in smart materials design. A comprehensive coverage of the literature is given and the author's view on where the field is likely to advance in the future is highlighted.

Contents
1 Introduction
2 Advances in inorganic-NCC hybrid nanocomposites
2.1 HAP-BC nanocomposites
2.2 Semiconductors-NCC nanocomposites
2.3 TiO2-NCC nanocomposites
2.4 Clay-NCC nanocomposites
2.5 Cellulose aerogel-based nanocomposites
3 Assembly of inorganic-NCC hybrid nancomposites
3.1 Electrospinning method
3.2 Templated mineralization
3.3 Sol-gel method
3.4 Solution casting method
3.5 Layer-by-layer method
4 NCC
4.1 Preparation
4.2 Properties
4.3 Arrangement and orientation
4.4 Chemical modification
4.5 Solvents
5 Innovation inspired by nature
5.1 Hierarchical and helical structure of cellulose
5.2 Chemoresponsive sea cucumber dermis
6 Conclusion and Outlook

Key words: inorganic, nanocrystalline cellulose, hybrid nanocomposites, assembly, functionality

CLC Number: 

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