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Progress in Chemistry 2011, Vol. 23 Issue (10): 2151-2159 Previous Articles   Next Articles

• Review •

Exploring Dynamics of Large Amplitude Internal Motions of Molecular Systems by Microwave Spectroscopy

Tang Shouyuan1,2, Fu Yujie3, Xia Zhining2,4, Li Baizhan1,2*   

  1. 1. Key Laboratory of the Three Gorges Reservoir Region's Eco-Environment of Ministry of Education, Chongqing University, Chongqing 400030, China;
    2. College of Urban Construction and Environmental Engineering, Chongqing University, Chongqing 400030, China;
    3. College of Pharmacy and Bioengineering, Chongqing University of Technology, Chongqing 400050, China;
    4. College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China
  • Received: Revised: Online: Published:
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Molecular group internal rotation and dynamics are of great significance in the expression of the activity and function of the molecules. Microwave spectroscopy which is capable of investigating the internal dynamics of molecular systems, the systematic structure of molecules, the conformation equilibria, weakly bound interactions, large amplitude motions, and quantum solvation mechanism, is a kind of technique with high sensitivity and resolution for studying group internal rotation dynamics and hyperfine structure of molecules. The large amplitude internal motions of molecular systems can be observed in their rotational spectra are reviewed in this paper. The typical motions are internal motion of methyl groups, internal motion of OH groups, inversion of amines and amides, organic ring motions and pseudorotation. Some our investigations are also discussed.

Contents
1 Introduction
2 Internal large amplitude motion of symmetric group
2.1 Internal large amplitude motion of single methyl group
2.2 Internal large amplitude motion of two and three methyl groups
2.3 Interplay of internal motion of methyl group with other motions
3 Internal motion of hydroxyl group
3.1 Internal large amplitude motion of hydroxyl group in organic ring
3.2 Internal motion of hydroxyl group in spherical top molecules
3.3 Internal motion of hydroxyl group in transient chiral molecules
4 Inversion of amines and other internal motions
5 Organic ring motions
5.1 Four- and five-membered ring puckering
5.2 Pseudorotation of organic ring
6 Conclusion and outlook

Key words: microwave spectroscopy, molecular systems, large amplitude motions, interaction, internal dynamics

CLC Number: 

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