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Progress in Chemistry 2011, Vol. 23 Issue (10): 2085-2094 Previous Articles   Next Articles

• Review •

Research Progress on Microporous Organic Polymers

Xu Shujun, Liang Liyun*, Li Buyi, Luo Yali, Liu Chengmei, Tan Bien*   

  1. Hubei Key Laboratory of Materials Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
  • Received: Revised: Online: Published:
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Microporous organic polymers (MOPs) are a new type of porous materials, which have advantages with synthetic diversity, chemical and physical stability, pore size controllability, and pore surface modifiability. In recent years, MOPs have attracted an enormous attention in energy gas storage and greenhouse gas capture due to their great potential physisorptive gas storage. This paper describes the structure and characteristics of MOPs. The four different kinds of MOPs, such as polymers of intrinsic microporosity (PIMs), hyper-crosslinked polymers (HCPs), covalent organic frameworks (COFs) and conjugated microporous polymers (CMPs) are introduced respectively, including the recent research progress and the relationship between structures and properties. The applications of MOPs such as catalysis, separations and gas storage are discussed briefly. We also discuss the development of MOPs in future.

Contents
1 Introduction
2 Polymers of intrinsic microporosity
2.1 Insoluble PIMs
2.2 Soluble PIMs
3 Hyper-crosslinked polymers
4 Covalent organic frameworks
5 Conjugated microporous polymers
6 Prospects

Key words: microporous organic polymers, hydrogen storage materials, porous materials

CLC Number: 

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