中文
Earlier issues
Announcement
More
Progress in Chemistry 2011, Vol. 23 Issue (0203): 595-604 Previous Articles   Next Articles

• Invited Article •

Research Progress of Hybrid Supercapacitor

Liu Haijing, Xia Yongyao*   

  1. Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Department of Chemistry, Fudan University, Shanghai 200433, China
  • Received: Revised: Online: Published:
PDF ( 5910 ) Cited
Export

EndNote

Ris

BibTeX

Compared with conventional secondary batteries, electrochemical supercapacitors exhibit the long cycling life and high power density, but with low energy density. In order to improve the energy density of supercapacitor, the most promising approaches are either to use an electrode material with large specific capacitance or increase its working voltage by utilizing a hybrid supercapacitor system which consist an activated carbon electrode and a battery elelctrode material (pseudo-capacitor material). The present paper introduces the development of the hybrid supercapacitor and the recent research on the electrode materials for hybrid supercapacitor. Many studies have been undertaken for the various hybrid supercapacitor systems to obtain higher energy density, coupling redox-active material electrodes with activated carbon electrode, such as activated carbon/NiOOH (FeOOH), activated carbon/graphite, activated carbon/metal oxides and activated carbon/polymer hybrid supercapacitors. Recently, Li-ion intercalated compounds Li4Ti5O12 and lithium-ion battery carbon materials are attracting much attention as positive electrode with a negative activated carbon electrode. At the same time, many researches focus on the various hybrid capacitor systems consisting of negative activated carbon electrode and positive aqueous Lithium-ion battery materials electrode, such as LiMn2O4, LiCoO2, LiTi2(PO4)3 and LiCo1/3Ni1/3Mn1/3O2.These hybrid supercapacitors are improved in energy density and also with the working voltage increased, comparing with the traditional activated carbon/activated carbon electrochemical double-layer capacitor. In the paper, the research situation and development tend of several kinds of hybrid systems and the currently studied relative materials are also introduced.

Key words: activated carbon, capacitor, hybrid supercapacitor, energy density, power density

CLC Number: 

[1] Conway B E. Electrochemical Supercapacitors, New York: Kluwer, Academic/Plenum Publishers, 1999
[2] Conway B E. J. Electrochem. Soc., 1991, 138(6): 1539-1548
[3] Zheng J P, Jow T R. J. Electrochem. Soc., 1995, 142(1): L6-L8
[4] Huggins R A. Solid State Ionics, 2000, 134 (1/2): 179-195
[5] 南俊民(Nan J M),杨勇(Yang Y),林祖赓(Lin Z G). 电源技术(Chinese Journal of Power Sources), 1996,20(4): 152-156
[6] Faggioli E, Rena P, Danel V. J. Power Sources, 1999, 84(2): 261-269
[7] Chu A, Braatz P. J. Power Sources, 2002, 112(1): 236-246
[8] Shukla A K, Aricò A S, Antonucci V. Renewable and Sustainable Energy Reviews, 2001, 5(2): 137-155
[9] Ktz R, Carlen M. Electrochim. Acta, 2000, 45(15/16): 2483-2498
[10] Conway B E, Pell W G. J. Power Sources, 2002, 105(2): 169-181
[11] Pell W G, Conway B E. J. Power Sources, 2001, 96(1): 57-67
[12] Zheng J P. J. Electrochem. Soc., 1995, 142(8): 2699-2703
[13] Zheng J P. J. Electrochem. Soc., 1995, 143(3): 1068-1072
[14] Sikha G, White R E, Popov B N. J. Electrochem. Soc., 2005, 152: A1682-A1693
[15] Wang Y G, Cheng L, Xia Y Y. J. Power Source, 2006, 153: 191-196
[16] Khomenko V, Raymundo-Pinero E, Beguin F. J. Power Source, 2006, 153: 183-190
[17] Cheng L, Li H Q, Xia Y Y. J. Solid State Electrochem., 2006, 10: 405-410
[18] Nohara S, Toshihide A A, Wada H, Furukawa N, Inoue H, Sugoh N, Iwasaki H, Iwakura C. J. Power Sources, 2006, 157: 605-609
[19] Amatucci G G, Badway F, Pasquier A D, Zheng T. J. Electrochem. Soc., 2001, 148: A930-A939
[20] Wang H Y, Yoshio M, Electrochem. Commun., 2006, 8: 1481-1486
[21] Yoshio M, Nakamura H, Wang H Y. Electrochemical and Solid State Letters, 2006, 9: A561-A563
[22] Wang Y G, Xia Y Y. J. Electrochem. Soc., 2006, 153: A450-A454
[23] Wang Y G, Luo J Y, Wang C X, Xia Y Y. J. Electrochem. Soc., 2006, 153: A1425-A1431
[24] Wang Y G, Lou J Y, Wu W, Wang C X, Xia Y Y. J. Electrochem. Soc., 2007, 154: A228-A234
[25] Wang Y G, Wang Z D, Xia Y Y. Electrochim. Acta, 2005, 50: 5641-5646
[26] 田志宏(Tian Z H),赵海雷(Zhao H L),李明(Li M),王治峰(Wang Z F),仇卫华(Qiu W H). 电池(Battery Bimonthly), 2006, 36(6), 469-471
[27] Stan Zurek. Ragone plot showing energy density vs. power density for various devices. Vector conversion from Image: Supercapacitors chart. png, from Maxwell Technologies. . http: //www.maxwell.com (The plot presented here is based on data provided by Maxwell Technologies.)
[28] Zheng J P. J. Electrochem. Soc., 2003, 150: A484-A492
[29] Varakin I N, Kiementov A D, Litvineko S V, Proceedings of the 8th International Seminar on Double-layer Capacitors and Similar Energy Storage Devices, Deerfield Beach, FL, 1998
[30] 刘志祥(Liu Z X),张密林(Zhang M L),闪星(Shan X). 电源技术(Chinese Journal of Power Sources),2001,25(5): 354-356
[31] Wang Y G, Yu L, Xia Y Y. J. Electrochem. Soc., 2006, 153: A743-A748
[32] Singhal A, Skandan G, Amatucci G. J. Power Sources, 2004, 129: 38-44
[33] Kavan L, Prochazka J, Spitler T M. J. Electrochem. Soc., 2003, 150: A1000-A1007
[34] Kanamura K, Umegaki T, Naito H. J. Appl. Electrochem., 2001, 31: 73-78
[35] Ohzuku T, Ueda A, Yamamoto N. J. Electrochem. Soc., 1995, 142: 1431-1435
[36] Pasquier D A, Laforgue A, Simon P. J. Power Sources, 2004, 125(1): 95-102
[37] Rao C V, Rambabu B. Solid State Ionics, 2010, 181: 839-843
[38] Cheng L, Liu H J, Zhang J J, Xiong H M, Xia Y Y. J. Electrochem. Soc., 2006, 153 (8): A1472-1477
[39] Cheng L, Li X L, Liu H J, Xiong H M, Zhang P W, Xia Y Y. J. Electrochem. Soc., 2007, 154: A228-A234
[40] Ando N, Taguchi M, Marumo C. Proceedings of 2010 International Conference on Advanced Capacitors, Kyoto Terrsa, Japan, 2010
[41] Luo J Y, Liu J L, He P, Xia Y Y. Electrochim. Acta, 2008, 53: 8128-8133
[42] Luo J Y, Xia Y Y. J. Power Sources, 2009, 186: 224-227
[43] Nam K W, Yoon W S, Kim K B. Electrochim. Acta, 2002, 47 (19): 3201-3209
[44] 汪形艳(Wang X Y), 王先友(Wang X Y), 黄伟国(Huang W G), 湘潭大学自然科学学报(Natural Science Journal of Xiangtan University), 2004, 26 (3): 287-290
[45] Jow T R, Zheng J P,Ding S P. The 7th International Seminaron Double Layer Capacitors and Similar Energy Storage Devices, Deerfield Beach,FL, 1997
[46] Evans D,Zheng J P,Roberson S. Proceedings of the 9th International Seminar on Double Layer Capacitors and Similar Energy Storage Devices, Deerfidd Beach, Florida, 1999
[47] 汪形艳(Wang X Y), 王先友(Wang X Y), 黄伟国(Huang W G). 电池(Battery Bimonthly), 2004, 34 (3): 192-193
[48] Kim H K, Seong T Y, Lim J H. J. Power Sources, 2001, 102 ( 1/ 2): 167-171
[49] Hu C C, Tsou T W. Electrochem. Commun., 2002, 4 (2): 105-109
[50] 庄凯 (Zhuang K),梁逵 (Liang K),李兵红(Li B H). 西华大学学报(自然科学版)(Journal of Xihua University(Natural Science Edition)),2006,25(1):6-7
[51] Pang S C, Anderson M A, Chapman T W. J. Electrochem Soc., 2000, 147 (2): 444-450
[52] 杜嬛(Du X), 王成扬(Wang C Y), 陈明鸣(Chen M M), 焦旸(Jiao Y). 无机材料学报(Journal of Inorganic Materials),2008,23(6): 1193-1198
[53] 汪形艳(Wang X Y), 王先友(Wang X Y), 侯天兰(Hou T L), 李俊(Li J), 黄庆华(Huang Q H). 化工学报(Chemical Industry and Engineering Progress),2006,57(2): 442-447
[54] 闪星(Shan X),张密林(Zhang M L),董国君(Dong G J). 电源技术(Chinese Journal of Power Sources),2002,26(2): 92-94
[55] Hong M S, Lee S H, Kim S W. Electrochem. Solid-State Lett., 2002, 5(10): A227-A230
[56] Volfkoviceh Y M, Shmatko P A. Proceedings of the 8th International Seminar on Double-layer Capacitors and Similar Energy Storage Devices, Deerfield Beach, FL, 1998
[57] Arbizzani C, Mastragostino M, Soavi F. J. Power Sources, 2001, l00(1/2):164-170
[58] Laforgue P, Simon P, Fauvarque J F. J. Eleetrochem. Soc., 2003, 150(5):A645-A651>
[44] 汪形艳(Wang X Y), 王先友(Wang X Y), 黄伟国(Huang W G), 湘潭大学自然科学学报(Natural Science Journal of Xiangtan University), 2004, 26 (3): 287—290

[45] Jow T R, Zheng J P,Ding S P. The 7th International Seminaron Double Layer Capacitors and Similar Energy Storage Devices, Deerfield Beach,FL, 1997

[46] Evans D,Zheng J P,Roberson S. Proceedings of the 9th International Seminar on Double Layer Capacitors and Similar Energy Storage Devices, Deerfidd Beach, Florida, 1999

[47] 汪形艳(Wang X Y), 王先友(Wang X Y), 黄伟国(Huang W G). 电池(Battery Bimonthly), 2004, 34 (3): 192—193

[48] Kim H K, Seong T Y, Lim J H. J. Power Sources, 2001, 102 ( 1/ 2): 167—171

[49] Hu C C, Tsou T W. Electrochem. Commun., 2002, 4 (2): 105—109

[50] 庄凯 (Zhuang K),梁逵 (Liang K),李兵红(Li B H). 西华大学学报(自然科学版)(Journal of Xihua University(Natural Science Edition)),2006,25(1):6—7

[51] Pang S C, Anderson M A, Chapman T W. J. Electrochem Soc., 2000, 147 (2): 444—450

[52] 杜嬛(Du X), 王成扬(Wang C Y), 陈明鸣(Chen M M), 焦旸(Jiao Y). 无机材料学报(Journal of Inorganic Materials),2008,23(6): 1193—1198

[53] 汪形艳(Wang X Y), 王先友(Wang X Y), 侯天兰(Hou T L), 李俊(Li J), 黄庆华(Huang Q H). 化工学报(Chemical Industry and Engineering Progress),2006,57(2): 442—447

[54] 闪星(Shan X),张密林(Zhang M L),董国君(Dong G J). 电源技术(Chinese Journal of Power Sources),2002,26(2): 92—94

[55] Hong M S, Lee S H, Kim S W. Electrochem. Solid-State Lett., 2002, 5(10): A227—A230

[56] Volfkoviceh Y M, Shmatko P A. Proceedings of the 8th International Seminar on Double-layer capacitors and Similar Energy Storage Devices, Deerfield Beach, FL, 1998

[57] Arbizzani C, Mastragostino M, Soavi F. J. Power Sources, 2001, l00(1/2):164—170

[58] Laforgue P, Simon P, Fauvarque J F. J. Eleetrochem. Soc., 2003, 150(5):A645—A651

 
[1] Qitong Wang, Jiale Ding, Danying Zhao, Yunhe Zhang, Zhenhua Jiang. Dielectric Polymer Materials for Energy Storage Film Capacitors [J]. Progress in Chemistry, 2023, 35(1): 168-176.
[2] Qi Qi, Peizhu Xu, Zhidong Tian, Wei Sun, Yangjie Liu, Xiang Hu. Recent Advances of the Electrode Materials for Sodium-Ion Capacitors [J]. Progress in Chemistry, 2022, 34(9): 2051-2062.
[3] Caiwei Wang, Dongjie Yang, Xueqing Qiu, Wenli Zhang. Applications of Lignin-Derived Porous Carbons for Electrochemical Energy Storage [J]. Progress in Chemistry, 2022, 34(2): 285-300.
[4] Kedi Cai, Shuang Yan, Tianye Xu, Xiaoshi Lang, Zhenhua Wang. Investigation of Electrode Materials for Lithium Ion Capacitor Battery [J]. Progress in Chemistry, 2021, 33(8): 1404-1413.
[5] Xiangye Li, Tianjiao Bai, Xin Weng, Bing Zhang, Zhenzhen Wang, Tieshi He. Application of Electrospun Fibers in Supercapacitors [J]. Progress in Chemistry, 2021, 33(7): 1159-1174.
[6] Yusen Ding, Pu Zhang, Hong Li, Wenhuan Zhu, Hao Wei. Research Status and Prospect of Li-Se Batteries [J]. Progress in Chemistry, 2021, 33(4): 610-632.
[7] Sha Tan, Jianzhong Ma, Yan Zong. Preparation and Application of Poly(3,4-ethylenedioxythiophene)∶Poly(4-styrenesulfonate)/Inorganic Nanocomposites [J]. Progress in Chemistry, 2021, 33(10): 1841-1855.
[8] Zhan Wu, Xiaohan Li, Aowei Qian, Jiayu Yang, Wenkui Zhang, Jun Zhang. Electrochromic Energy-Storage Devices Based on Inorganic Materials [J]. Progress in Chemistry, 2020, 32(6): 792-802.
[9] Shaofei Zhao, Peng Liu, Gao Cheng, Lin Yu, Huaqiang Zeng. Preparation and Pseudocapacitor Properties of Self-Supported Nickel Sulfides Electrode Materials [J]. Progress in Chemistry, 2020, 32(10): 1582-1591.
[10] Guobin Tong, Lei E, Zhou Xu, Chunhui Ma, Wei Li, Shouxin Liu. Preparation, Modification and Application of Carbon Materials Based on Ionic Liquids [J]. Progress in Chemistry, 2019, 31(8): 1136-1147.
[11] Shaoming Qiao, Naibao Huang, Zhengyuan Gao, Shixian Zhou, Yin Sun. Nickel-Manganese Binary Metal Oxide as Electrode Materials for Supercapacitors [J]. Progress in Chemistry, 2019, 31(8): 1177-1186.
[12] Jie Liu, Yuan Zeng, Jun Zhang, Haijun Zhang, Jianghao Liu. Preparation, Structures and Properties of Three-Dimensional Graphene-Based Materials [J]. Progress in Chemistry, 2019, 31(5): 667-680.
[13] Changyuan Bao, Jiajun Han*, Jinning Cheng, Ruitao Zhang. Electrode Materials Blended with Graphene/Polyaniline for Supercapacitor [J]. Progress in Chemistry, 2018, 30(9): 1349-1363.
[14] Kai Han, Nuo Li, Hongqi Ye, Kai Han*. Synthesis of Two-Dimensional MXene and Their Applications in Electrochemical Energy Storage [J]. Progress in Chemistry, 2018, 30(7): 932-946.
[15] Di Xu, Hujiang Shen*, Huihui Yuan, Wei Wang, Junjie Xie. Poly(3, 4-Ethylenedioxythiophene) Based Electrode Materials: Preparation, Modification and Application in Electronic Devices [J]. Progress in Chemistry, 2018, 30(2/3): 252-271.
Viewed
Full text


Abstract

Research Progress of Hybrid Supercapacitor