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Progress in Chemistry 2011, Vol. 23 Issue (0203): 501-508 Previous Articles   Next Articles

• Review •

Pt-Based Intermetallic Compounds as Electrocatalysts

Li Xiang1, An Li1, Zhang Lijuan1, Li Fan1, Wang Xiayan1, Xia Dingguo2*   

  1. 1. College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China;
    2. College of Engineering, Peking University, Beijing 100871, China
  • Received: Revised: Online: Published:
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In order to improve catalytic activity and stability, alloying Pt with a non-noble metal has proved to be a successful strategy for the development of new electrocatalysts for low temperature fuel cell. An alloy is a mixture containing two or more metallic elements or metallic and nonmetallic elements usually fused together or dissolving into each other when molten. Solid solution is the alloy when two metals (or nonmetallic) are completely soluble in liquid state and also completely soluble in solid state. Usually, the atomic positions and stoichiometric of the solid solution are uncertain, for example, commercial electrocatalyst PtRu alloy. Intermetallic compound is a compound of two or more metallic elements or metallic and nonmetallic elements. Usually, the atomic positions and stoichiometric of the intermetallic compound are fixed. Pt-based intermetallic compounds have been paid more and more attentions by researchers due to its many excellent properties. In this review paper, we present the recent progress of Pt-based intermetallic compounds used in low temperature fuel cell. The synthesis method and some Pt-based intermetallic compounds are present. The future development of this research field is prospected.

Key words: intermetallic compounds, electrocatalyst, low temperature fuel cell, electrocatalysis

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