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Progress in Chemistry 2011, Vol. 23 Issue (0203): 410-417 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

Ordered/Disordered Rocksalt Structured Li1+xM1-xO2 Cathode Materials for Li-Ion Battery

Zhang Lianqi1*, Xiao Chengwei2, Yang Ruijuan1   

  1. 1. School of Materials Science and Engieering, Tianjin University of Technology, Tianjin 300384, China;
    2. College of Chemistry, Nankai University, Tianjin 300071,China
  • Received: Revised: Online: Published:
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Recently, Li excess (or Li-rich) layered ordered/disordered materials for Li-ion battery exhibited amazing electrochemical performances and thus received extensive attention. They all can be formulated as Li1+xM1－xO2 (M can be one or multi-metal ions, x≥0). However, the complexity of composition and structure in most of Li1+xM1－xO2 compounds (M usually represents multi-metal ions such as M= Ni1-x-yCoxMny and materials can present different interlayer/intralayer cations ordering in structure) and variability of valence in some metal ions ( different valences in some metals ions such as Ni and Mn may form depending on conditions) easily make readers confused in understanding nature of those materials. The clear interpretation of those materials' nature in references is still not enough at present and even some materials were misinterpreted in some references. In this review, on the basis of their structure, the nature of Li excess (or Li-rich) layered ordered/disordered materials was firstly described precisely according to LiAO2-Li2BO3 solid solution. In combination with our research results, it was further discussed how to utilize phase diagram to assist readers to understand those complicated Li1+xM1－xO2 materials and further design new compounds. Some recent important progress on these materials was also commented.

Key words: Li-ion battery, Li1+xM1－xO2 cathode materials, LiAO2-Li2BO3 solid solution, phase diagram

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