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Progress in Chemistry 2011, Vol. 23 Issue (0203): 390-400 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

Methods on Investigating Properties of Electrode/Electrolyte Interfaces in Lithium-Ion Batteries

Qin Yinping1, Zhuang Quanchao1*, Shi Yueli1, Jiang Li1, Sun Zhi1   

  1. 1. School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, China;
    2. State Key Lab for Physical Chemistry of Solid Surfaces, Department of Chemistry, Xiamen University, Xiamen 361005, China
  • Received: Revised: Online: Published:
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The rechargeable lithium-ion battery has been extensively used in mobile communication and portable instruments due to its many advantages, such as high volumetric and gravimetric energy density and low self-discharge rate. In addition, it is the most promising candidate as the power source for (hybrid) electric vehicles and stationary energy storage. The properties of electrode/electrolyte interfaces play an important role in the electrochemical performance of the electrode material and a battery, such as the capacities, irreversible charge “loss”, rate capability and cyclability. In present paper, the methods to investigate the properties of electrode/electrolyte interfaces, for example, traditional electrochemical methods, microscopy methods, spectroscopic methods, electrochemical quartz crystal microgravimetry (EQCM) are summarized. The principles, advantages and disadvantages of these methods and their applications in investigating the properties of electrode/electrolyte interfaces, especially the progress in the combination of these methods to investigate the properties of electrode/electrolyte interfaces, are introduced in detail, and these methods will be considerable to study the new materials or the traditional materials for lithium-ion batteries in the future.

Key words: lithium-ion batteries, solid electrolyte interphase (SEI), methods

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