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Progress in Chemistry 2011, Vol. 23 Issue (0203): 318-327 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

Si-Based Materials as the Anode of Lithium-Ion Batteries

Tao Zhanliang, Wang Hongbo, Chen Jun*   

  1. Key Laboratory of Advanced Energy Material Chemistry of Ministry of Education, Nankai University, Tianjin 300071, China
  • Received: Revised: Online: Published:
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Silicon-based materials are promising anode materials for lithium-ion batteries (LIBs) due to their high-energy capacity. However, the commercialization of silicon-based materials as the anode of LIBs has been hindered by the huge volume change, poor cycle life and low initial coulombic efficiency during the charge/discharge process. This article reviews the change of both the crystal structure and the surface/interface of Si-based material during the intercalation/deintercalation of lithium, and the methods improving the electrochemical performance. In addition, the prospects of silicon-based materials as the anode of LIBs are also discussed.

Key words: silicon-based materials, anode materials, lithium ion batteries

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