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Progress in Chemistry 2011, Vol. 23 Issue (01): 192-201 Previous Articles   Next Articles

• Review •

Synthesis,Self-Assembly,and Applications of Polyferrocenylsilane Diblock Copolymers

Fan Lihui1, Zhou Yongfeng1, Yan Deyue1, Yang Jintian2, Ji Bing2   

  1. 1. School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, China;
    2. School of Life Science, Huzhou Teachers College, Huzhou 313000, China
  • Received: Revised: Online: Published:
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Ferrocene molecules possess special optical,electrical and magnetic properties due to the unique aromatic structure and transition metal Fe,and have been one of the focuses of scientific research and technology application in recent years.Polyferrocenylsilanes (PFS) are a novel class of transition metal-containing macromolecules with the backbone that consists of ferrocene and organosilane units.The PFS diblock copolymers are attracting intense current attentions recently because of their controllable molecular weight and varied self-assembly morphologies.This paper provides an overview of the works including the synthesis,self-assembly and potential applications of PFS-based diblock copolymers.For example,this article has introduced the living anionic ring-opening polymerization (ROP) and the two-steps anionic ROP as well as the polymerization mechanisms for the synthesis of all kind of PFS-based diblock copolymers.On the other hand,the self-assembly of this kind of diblock copolymers in selective solvents has also been summarized,it is found the polymers will self-assemble into well defined supramolecular micellar aggregates because of phase separation,such as cylinders,tubes,spheres,tapes and brushes.Especially,the formations of the micelles can also be named as a “living self-assembly” progress like the living polymerization.Some of the micelles can change to other morphology if some stimulations occurred,and also can be spatially selective functionalized to obtain specific properties.At last,some specific applications of PFS diblock copolymers and the assemblies in the area including drug delivery,nano-materials,and specific catalysts are illustrated and the future prospects for PFS diblock copolymers science are discussed in this paper.

Key words: polyferrocenylsilane, block copolymer, self-assembly, application

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