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Progress in Chemistry 2010, Vol. 22 Issue (11): 2224-2231 Previous Articles   Next Articles

• Review •

Bio-inspired Mineralization Process in Gel Media

Shi Ying   Geng Jiaqing   Yang Dong   

  1. (Key Laboratory of Systems Bioengineering, Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China)
  • Received: Revised: Online: Published:
  • Contact: Yang Dong E-mail:dongyang@tju.edu.cn
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This review introduces the research progress of the bio-inspired mineralization process in the gel medium. Bio-inspired mineralization is the leading edge and hotspot of the research in the fields including chemistry, biology and materials science at present. Recently, more and more efforts prove that the biomolecules, such as the protein and polysaccharide, usually form the gelatinous reticular matrix in the organism, which can influence the biomineralization process. Therefore, the research of bio-inspired mineralization processes in the gel medium is important to understand the biomineralization mechanism, and guide the design and synthesis of advanced functional materials. Until now, the bio-inspired mineralization process in the gel media including the natural and man-made macromolecule gel, supermolecule hydrogel, and inorganic gel, and so on, has been investigated. The current experimental results show that the gel media control the morphology of inorganic crystals by primarily inhibiting the diffusion of reactant ions in their network structure and doping into the formed crystals. Moreover, the bio-inspired mineralization in the gel medium cooperating with organic matrices, such as water-soluble additives and self-assembled mono-layers (SAMs), exhibits different characters from that in aqueous solution. In addition, this review also introduces several opinions about the bio-inspired mineralization mechanism of inorganic crystals formed in the gel medium. At last, the development trend of the research and application in this field is expected.

Contents
1 Introduction
2 Bio-inspired mineralization in gel media
2.1 Natural macromolecule gel
2.2 Man-made macromolecule gel
2.3 Supermolecule hydrogel
2.4 Inorganic gel
3 Effect of organic matrices on bio-inspired mineralization in gel media
3.1 Water-soluble additives
3.2 Self-assembled mono-layers, SAMs
4 Mechanism of bio-inspired mineralization in gel medium
5 Conclusions and outlook

Key words: bio-inspired mineralization, gel, inorganic crystal, morphology control

CLC Number: 

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