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Progress in Chemistry 2010, Vol. 22 Issue (11): 2173-2178 Previous Articles   Next Articles

• Review •

Functionlization of Honeycomb-Patterned Films

Jin Jing   Wan Ling-Shu**  Ke Beibei   Xu ZhiKang   

  1. (MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China)
  • Received: Revised: Online: Published:
  • Contact: Wan LingShu E-mail:lswan@zju.edu.cn
  • Supported by:

    ;NSFC

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Honeycomb-patterned films by breath figure method have received considerable interest in recent years. This method is based on evaporative cooling and subsequent water-droplet templating to form an ordered array of breath figures, which has many advantages, for example, it is simple and cost-saving, and no extra steps are needed to remove the water templates. This review comprehensively summarizes the advances in the functionalization of honeycomb-patterned films. A series of methods are highlighted, which include hierarchical self-assembly, controlled surface grafting, immobilization of bioactive molecules, ultraviolet-induced and chemical crosslinking, template-guided film formation, and surface filling. The functionalized honeycomb-patterned films have been found great potential applications in various fields, such as microreactor, picoliter beaker, template, cell culture media, separation membrane, superhydrophobic surface, refractive-index materials, and photovoltaic materials.

Contents
1 Introduction
2 Functionalization methods for honeycomb-patterned films
2.1 In-situ hierarchical self-assembly
2.2 Controlled surface grafting
2.3 Immobilization of bioactive molecules
2.4 Ultraviolet-induced and chemical crosslinking
2.5 Template-guided film formation
2.6 Surface filling
2.7 Other methods
3 Conclusion and outlook

Key words: honeycomb-patterned films, breath figure method, funtionalization, self-assembly

CLC Number: 

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