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Progress in Chemistry 2010, Vol. 22 Issue (11): 2156-2164 Previous Articles   Next Articles

• Review •

Novel Molecular Machine Based on the Cyclodextrin—Fullerene Coupling System

Sun Tao Zhang Huacheng Li Yueming  Xin Feifei   Kong Li   Hao Aiyou**   

  1. (School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China)
  • Received: Revised: Online: Published:
  • Contact: Sun Tao E-mail:stred@mail.sdu.edu.cn
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Supramolecular chemistry is a hot research topic in current chemistry. It is more attractive to build machines in a nanometer scale by mimicking the processes in macro-scale through the supramolecular way. Being different from the traditional “motile” molecular machines, the novel “processing” molecular machines based on the cyclodextrin-fullerene coupling system focus on a “recognition-capture-processing-release” procedure, but not on the position changes in and between molecules. This new molecular machine will supply a new approach in the area of enzyme mimic, biological process research, photo-immobilization, etc. Here, the development of cyclodextrin-fullerene coupling system is reviewed. Firstly, the synthesis of different kinds of cyclodextrin-fullerene coupling systems, including the synthesis clues, approaches methods and characterization, is introduced. Then, the application of the system is emphatically described, including molecular recognition, DNA cleavage and electron transfer, etc. At last, combination of current development of the system, the prospects are pointed out.

Contents 
1.Introduction
2Synthesisi of cyclodextrin-fullerene coupling system
2.1 Synthesisi of the 1:1 cyclodextrin-fullerene coupling system
2.2 Synthesisi of the 2:1 cyclodextrin-fullerene coupling system 
3 Application of of cyclodextrin-fullerene coupling system
3.1 Molecule recognition
3.2 DNA cleavage
3.3 Research of electron transfer 
4 Prospects

Key words: cyclodextrins, Fullerene, Coupling system, molecular machine

CLC Number: 

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