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Progress in Chemistry 2010, Vol. 22 Issue (11): 2089-2098 Previous Articles   Next Articles

Special Issue: 金属有机框架材料

• Review •

Methods of Creating Active sites in MOF and Catalytic Explorations

liu lili   zhang Xin**   Xu Chunming**   

  1. （State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing Changping, 102249）
  • Received: Revised: Online: Published:
  • Contact: zhang Xin E-mail:zhangxin@cup.edu.cn
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Due to its unique structural characteristics (the high specific surface area, tailoring structure properties and 100% utilization of exposed metal ions), metal organic framework (MOF) materials have drawn great attention on catalysis in recent years. However, the drawbacks of no open metal ions and poor thermal stability limit their application in catalysis. This tutorial review presents recent developments of the emerging field of MOF based catalysis. We summarize four distinct strategies: pre-synthesis method, post-synthesis modification, impregnation method and precipitation method, which have been utilized to create catalytic active sites in MOF. Examples of the catalytic reactions based on the created active sites in the MOF are then followed. It has been shown that the pre-synthesis method has been widely used in creating catalytic active sites in the MOF. MOF with active sites created by the pre-synthesis and the post-synthesis modification method in the MOF may act as “shape selective catalysis” as zeolite. Usually as a Lewis acid catalyst, MOFs are capable of being very active for many reactions, especially at temperatures below 100 oC. A critical comment on these methods and catalytic explorations has been addressed in order to guide the newcomer to this field.

 Contents
1 Introduction
2 The method of creating active sites in MOF and its application in catalysis
2.1 Pre-synthesis method and catalytic explorations
2.2 Post-synthesis modification and catalytic explorations
2.3 Impregnation method and catalytic explorations
2.4 Precipitation method and catalytic explorations
3 Conclusion and outlook

Key words: metal-organic framework (MOF), active sites, catalysis, catalytic reactions

CLC Number: 

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