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Progress in Chemistry 2010, Vol. 22 Issue (10): 2071-2078 Previous Articles   

• Review •

Activated Carbon Catalyzed Peroxide Degradation of Organic Pollutants in Water

Yang Xin  Yang Shiying**  Shao Xueting  Wang Leilei  Niu Rui   

  1. (Key Laboratory of Marine Environment and Ecology, Ministry of Education; College of Environmental Science and Engineering, Ocean University of China, Qingdao 266100, China)
  • Received: Revised: Online: Published:
  • Contact: Yang Shiying E-mail:shiningpup@hotmail.com
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H2O2 can obviously be catalyzed by activated carbon (AC) on the AC surface, forming the free radicals of hydroxyl radical (•OH). As is to known,persulfate (PS) is similar to H2O2 in structure, so PS may be catalyzed by AC too, involving the formation of free radicals of sulfate radical (SO4−•). AC/peroxide (H2O2 or PS) combined system will be an efficient advanced oxidation technology of removing organic pollutants in water or wastewater. This paper, for the first time, reviews the research progress of the combined system in degrading organic pollutants, including AC/H2O2, AC/Fenton, AC/H2O2/UV light, AC/H2O2/microwave, AC/Fenton/microwave, AC/wet H2O2 oxidation, as well as AC/PS, AC/PS/metal ion, and AC/PS/ microwave. Both the interaction between AC and peroxide, and the prospects of AC/peroxide technology are also discussed.

Contents
1 Combined systems of AC and H2O2
1.1 AC/H2O2
1.2 AC/Fenton
1.3 AC/H2O2/UV Light
1.4 AC/H2O2/Microwave, AC/Fenton/Microwave
1.5 AC/Wet H2O2 Oxidation
2 Combined systems of AC and PS
2.1 AC/PS
2.2 AC/PS/metal Ion
2.3 AC/PS/microwave
3 Interaction between AC and peroxide
3.1 Impact of AC on peroxide
3.2 Impact of peroxide on AC
4 Conclusions and outlook

Key words: activated carbon, hydrogen peroxide, persulfate, catalysis, free radicals, degradation of organic pollutants

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