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Progress in Chemistry 2010, Vol. 22 Issue (10): 2060-2070 Previous Articles   Next Articles

• Review •

Preparation of Nanocrystalline Cellulose

Li Wei   Wang Rui   Liu Shouxin**   

  1. (Key Laboratory of Biological Materials of Ministry of Education , Northeast Forestry University , Harbin 150040 , China)
  • Received: Revised: Online: Published:
  • Contact: Li Wei E-mail:xinyang19820927@163.com
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Nanocrystalline cellulose has become a hotspot in nanotechnology field for its advantages of abundant, renewable, biodegradable and excellent mechanical properties. The preparation methods of NCC are summarized, especially introducing the chemical and mechanical preparation methods. Meanwhile the surface modification of NCC is reviewed, also the application of the NCC for preparing nanocomposites are summarized and the application of NCC on reinforcing composites are reviewed in detail. Finally, the future development of NCC is prospected.

Contents
1 Introduction
2 Preparation of NCC
2.1 Chemical method
2.2 Mechanical method
2.3 Biologic method
2.4 Solvent method
2.5 Electrospinning method
2.6 Ionic liquid method
3 Surface modification of NCC
3.1 Sulfonation
3.2 Carboxylation
3.3 Grafting
3.4 Acetylation
3.5 Silanization
3.6 Surfactant treatment
3.7 Polyelectrolyte treatment
4 Applications of NCC in composites
4.1 High qualities reinforcement composites and film materials
4.2 Medical materials
4.3 Optical materials
4.4 Template materials
4.5 Other applications
5 Outlook

[1 ] Wegner T H,Jones P E. Cellulose,2006,13: 115—118
[2 ] Lahiji R R,Reifenberger R,Raman A,Rudie A,Moon R J.
NSTI Nanotechnology Conference and Trade Show
Nanotechnology,2008,2: 704—707
[3 ] Pandey J K, Chu W S, Kim C S, Lee C S, Ahn S H.
Composites: Part B,2009,40: 676—680
[4 ] Lima M M D S,Borsali R. Macromol. Rapid Commun. ,2004,
25: 771—787
[5 ] Helbert W, Sugiyama J, Ishira M, Yamanaka S. J.
Biotechnol. ,1997,57(1 /3) : 29—37
[6 ] Hamad W. The Canadian Journal of Chemical Engineering,
2006,84(10) : 513—519
[7 ] Sturcova A,Davies G R,Eichhorn S J. Biomacromolecules,
2005,6: 1055—1061
[8 ] Orts W J,Shey J,Imam S H,Glenn G M,Guttman M E,Revol
J F. J. Polymers Environ. ,2005,13(4) : 301—306
[9 ] Petersson L,Kvien I,Oksman K. Composites Sci. & Technol. ,
2007,67: 2535—2544
[10] Noorani S,Simonsen J,Atre S. Cellulose,2007,14: 577—584
[11] Dalmas F,Chazeau L,Gauthier C,Cavaille J Y,Dendievel R.
Polymer,2006,47(8) : 2802—2812
[12] Samir M A S A,Alloin F,Dufresne A. Biomacromolecules,
2005,6(2) : 612—626
[13] Revol J F,Bradford H,Giasson J,Marchessault R H,Gray D
G. Int. J. Biol. Macromol. ,1992,14: 170—172
[14] Fleming K,Gray D G,Matthews S. Chem. Eur. J. ,2001,7
(9) : 1831—1835
[15] Fleming K,Gray D G, Prasannan S,Matthews S. J. Am.
Chem. Soc. ,2000,122(21) : 5224—5225
[16] Battista O A,Coppick S,Howsmon J A,Morehead F F,Sisson
W A. Ind. Eng. Chem. ,1955,48: 333—335
[17] Marchessault R H,Morehead F F,Koch M J. J. Colloid Sci. ,
1961,16: 327—344
[18] Araki J,Wada M,Kuga S,Okano T. Colloid Surfaces A,1998,
142: 75—82
[19] Dong X M,Revol J F,Gray D G. Cellulose,1998,5: 19—32
[20] Grunert M,Winter W T. J. Polym. Environ. ,2002,10: 27—
30
[21] Favier V,Chanzy H,Cavaille J Y. Macromolecules,1995,28:
6365—6367
[22] Imai T, Boisset C, Samejima M, Igarashi K, Sugiyama J.
Federation of European Biochemical Societies Letters, 1998,
432: 113—116
[23] de Rodriguez N L G,Thielemans W,Dufresne A. Cellulose,
2006,13: 261—270
[24] Ranby B G. Discussions Faraday Society,1952,11: 158—164
[25] Beck-Candanedo S,Roman M,Gray D G. Biomacromolecules,
2005,6: 1048—1054
[26] Zhang J G,Elder T J,Pu Y Q,Ragauskas A J. Carbohydrate
Polymers,2007,69: 607—611
[27] Moran J I,Alvarez V A,Cyras V P,Vazquez A. Cellulose,
2008,15: 149—159
[28] Marchessault R H,Morehead F F,Koch M J. Colloid Sci. ,
1961,16: 327—344
[29] Bondeson D,Mathew A, Oksman K. Cellulose,2006,13:
171—180
[30] Filson P B,Dawson-Andoh B E. Bioresource Technology,2009,
100: 2259—2264
[31] Bai W,Holbery J,Li K C. Cellulose,2009,16: 455—465
[32] Ranby B G. Ark. Kemi. ,1952,4: 249—257
[33] Ranby B G. Ark. Kemi. ,1952,4: 241—248
[34] Terech P,Chazeau L,Cavaille J Y. Macromolecules,1999,32:
1872—1875
[35] Araki J,Kuga S. Langmuir,2001,17: 4493—4496
[36] Tokoh C,Takabe K,Fujita M,Saiki H. Cellulose,1998,5:
249—261
[37] Roman M,Winter W T. Biomacromolecules,2004,5: 1671—
1677
[38] Nakagaito A N,Yano H. Appl. Phys. A-Mater. Sci. Proc. ,
2004,78(4) : 547—552
[39] Chakraborty A,Sain M,Kortschot M. Holzforschung,2005,59
(1) : 102—107
[40] Iwamoto S,Nakagaito A N,Yano H,Nogi M. Appl. Phys. A,
2005,81: 1109—1112
[41] Bruce D M, Hobson R N, Farrent J W, Hepworth D G.
Composites Part A-Applied Sci. Manuf. , 2005, 36 ( 11 ) :
1486—1493
[42] Dinand E,Chanzy H,Vignon M R. Cellulose,1996,3: 183—
188
[43] Stenstad P,Andresen M,Tanem B S,Stenius P. Cellulose,
2008,15(1) : 35—45
[44] Bhantnagar A,Sain M J. Reinforced Plastics Composites,2005,
24(12) : 1259—1268
[45] Leitner J,Hinterstoisser B,Wastyn M,Keckes J,Gindl W.
Cellulose,2007,14: 419—425
[46] Dufresne A,Cavaille J Y,Vignon M R. J. Appl. Polym. Sci. ,
1997,64: 1185—1194
[47] Wagberg L,Decher G,Norgren M,Lindstrom T,Ankerfors M.
Langmuir,2008,24(3) : 784—795
[48] Paakko M,Ankerfors M,Kosonen H,Nykanen A,Ahola S,
Osterberg M,Ruokolainen J,Laine J,Larsson P Y,Ikkala Q,
Lindstrom Y. Biomacromol. ,2007,8(6) : 1934—1941
[49] Janardhnan S,Sain M. BioRes. ,2006,1(2) : 176—188
[50] Alemdar A,Sain M. Biores. Technol. ,2008,99 (6 ) : 1664—
1671
[51] Wang B,Sain M. Polymer International,2007,56 ( 4 ) : 538—
546
[52] Yamanaka S,Watanabe K,Kitamura N. Journal of Material
Science,1989,24: 3141—3145
[53] Ross P,Mayer R,Benziman M. Microbiological Reviews,1991,
55(1) : 35—58
[54] Uraki Y, Morito M, Kishimoto T, Sano Y. Holzforschung,
2002,56(4) : 341—347
[55] Bae S,Shoda M. Biotechnol. Prog. ,2004,20: 1366—1371
[56] Ishihara M,Matsunaga M,Hayashi N,Tisler V. Enzyme and
Microbial Technology,2002,31(7) : 986—991
[57] Oksman K,Mathew A P,Bondeson D,Kvien I. Composites Sci.
Technol. ,2006,66(15) : 2776—2784
[58] Nelson K,Deng Y L. Macromol. Mater. Eng. ,2007,292(10 /
11) : 1158—1163
[59] Kulpinski P. J. Appl. Polymer Sci. ,2005,98 ( 4 ) : 1855—
1859
[60] Kim C W,Kim D S,Kang S Y,Marquez M,Joo Y L. Polymer,
2006,47(14) : 5097—5107
[61] Olivier H. J. Mol. Catalysis A: Chemical,1999,146 ( 1 /2 ) :
285—289
[62] Gindl W,Keckes J. Polymer,2005,46(23) : 10221—10225
[63] Kilpelainen I,Xie H,King A,Granstrom M,Heikkinen S,
Argyropoulos D S. J. Agric. Food Chem. ,2007,55 ( 22 ) :
9142—9148
[64] Sui X,Yuan U,Yuan W,Zhou M. Chemistry Letters,2008,37
(1) : 114—115
[65] Wgberg L,Decher G,Norgren M,Lindstrom T,Ankerdors M,
Axnas K. Langmuir,2008,24(3) : 784—795
[66] Montanari S,Rountani M,Heux L,Vignon M R. Macromol. ,
2005,38(5) : 1665—1671
[67] Saito T,Kimura S,Nishiyama Y, Isogai A. Biomacromol. ,
2007,8(8) : 2485—2491
[68] Habibi Y,Chanzy H,Vignon M R. Cellulose,2006,13 ( 6 ) :
679—687
[69] Mishra S,Naik J B. Polymer-Plastics Technol. Eng. ,2005,44
(4) : 663—675
[70] Nenkova S, Dobrilova C, Natov M, Vasileva S, Velev P.
Polym. and Polym. Comp. ,2006,14(2) : 185—194
[71] Kamel S,Adel A M,El-Sakhawy M,Nagieb Z A. J. Appl.
Polymer Sci. ,2008,107(2) : 1337—1342
[72] Stenstad P,Andresen M,Tanem B S,Stenius P. Cellulose,
2008,15(1) : 35—45
[73] Hubbe M A,Wagle D G,Ruckel E R. US 5958180,1999
[74] Matuana L M,Woodhams R T,Balatinecz J J, Park C B.
Polymer Composites,1998,19(4) : 446—455
[75] Habibi Y,Dufresne A. Biomacromol. ,2008,9 ( 7 ) : 1974—
1980
[76] Cai X L,Riedl B,Ait-Kadi A. J. polymer Sci. B-Polymer
Phy. ,2003,41(17) : 2022—2032
[77] Dou H J,Yang W H,Sun K. Chem. Lett. ,2006,35 ( 12 ) :
1374—1375
[78] Li X,Tabil L G,Panigrahi S. J. Polym. Environ. ,2007,15:
25—33
[79] Caulfield D F,Koutsky J A,Quillen D T. Forest Prod. Soc. ,
1993,128—134
[80] Mwaikambo L Y, Ansell M P. Angew. Makormol. Chem. ,
1999,272: 108—116
[81] Kim D Y,Nishiyama Y,Kuga S. Cellulose,2002,9 ( 3 ) :
361—367
[82] Ifuku S,Nogi M,Abe K,Handa K,Nakatsubo F,Yano H.
Biomacromol. ,2007,8(6) : 1973—1978
[83] Gousse C,Chanzy H,Cerrada M L,Fleury E. Polymer,2004,45(5) : 1569—1575
[84] Panaitescu D M,Donescu D,Brecu C,Vuluga D M,Iorga M,
Ghiurea M. Polymer Eng. Sci. ,2007,47(8) : 1228—1234
[85] Castellano M,Gandini A,Fabbri P,Belgacem M N. J. Colloid
Interface Sci. ,2004,273(2) : 505—511
[86] Gradwell S E,Renneckar S,Esker A R,Heinze T,Gatenholm
P,Vaca-Garcia C,Glasser W. Comptes Rendus Biol. ,2004,
327(9 /10) : 945—953
[87] Ljungberg N, Bonini C, Bortolussi F, Boisson C,Heux L,
Cavaille J Y. Biomacromol. ,2005,6(5) : 2732—2739
[88] Ahola S,Osterberg M, Laine J. Cellulose,2008,15 ( 2 ) :
303—314
[89] Hubbe M A. J. Pulp Paper Sci. ,2005,31(4) : 159—166
[90] Hajji P,Cavaille J Y,Favier V,Gauthier C,Vigier G. Polymer
Composites,1996,17(4) : 612—619
[91] Ruiz M M,Cavaille J Y,Dufresne A,Graillat C,Gerard J F.
Macromol. Symp. ,2001,169: 211—222
[92] Bhatnagar A,Sain M J. Reinforced Plastics Composites,2005,
24(12) : 1259—1268
[93] Wu Q,Henrihsson M,Liu X,Berglund L A. Biomacromol. ,
2007,8(12) : 3687—3692
[94] Nakagaito A N,Yano H. Appl. Phys. A-Mater. Sci. Proc. ,
2004,78(4) : 547—552
[95] Nakagaito A N,Iwamoto S,Yano H. Appl. Phys. A- Mater.
Sci. Proc. ,2005,80(1) : 93—97
[96] Nakagaito A N,Yano H. Appl. Phys. A-Mater. Sci. Proc. ,
2005,80(1) : 155—159
[97] Wang B,Sain M. Composites Sci. Technol. ,2007,67 ( 11 /
12) : 2521—2527
[98] Favier V,Canova G R,Cavaille J Y,Chanzy H,Dufresne A,
Gauthier C. Polymer Adv. Tech. ,1995,6(5) : 351—355
[99] Noorani S,Simonsen J,Atre S. Cellulose,2007,14: 577—584
[100] Cao X D,Dong H,Li C M. Biomacromol. ,2007,8(3) : 899—
904
[101] Pu Y Q, Zhang J G, Elder T, Deng Y L, Gatenholm P,
Ragauskas A J. Composites Part B: Engineering,2007,38:
360—366
[102] Dufresne A,Cavaille J Y,Helbert W. Polymer Composites,
1997,18(2) : 198—210
[103] Dong S P,Roman M. J. Am. Chem. Soc. ,2007,129 ( 45 ) :
13810—13811
[104] Czaja W K, Young D J, Kawecki M, Brown R W.
Biomacromol. ,2007,8(1) : 1—12
[105] Millon L E,Wan W K. J. Biomed. Mater. Res. Part B—Appl.
Biomater. ,2006,79B(2) : 245—253
[106] Bodin A,Backdahl H,Risberg B,Gatenholm P. Tissue Eng. ,
2007,13(4) : 885—885
[107] Nogi M,Ifuku S,Abe K,Handa K,Nakagaito A N,Yano H.
Appl. Phys. Lett. ,2006,88(13) : art. no. 133124
[108] Nogi M,Abe K,Handa K,Nakatsubo F,Ifuku S,Yano H.
Appl. Phys. Lett. ,2006,89(23) : art. no. 233123
[109] Bochek A M,Ten'kovtsev A V,Dudkina M M,Lukoshkin V N,
Matneeva G N,Sukhanova T E. Polymer Sci. Ser. B,2004,46
(3 /4) : 109—112
[110] Cranston E D,Gray D G. Biomacromol,2006,7 ( 9 ) : 2522—
2530
[111]Wang N,Ding E Y,Cheng R S. Langmuir,2008,24(1) : 5—
8
[112] Dujardin E,Blaseby M,Mann S J. Mater. Chem. ,2003,13
(4) : 696—699
[113] Shin Y,Exarhos G J. Mater. Lett. ,2007,61(11 /12) : 2594—
2597
[114] Shin Y,Blackwood J M,Bea I T,Arey B W,Exarhos G J.
Materials Letter,2007,61: 4297—4300
[115] Zhou Y,Ding E Y,Li W D. Materials Letters,2007,61:
5050—5052
[116] Agarwal M,Lvov Y,Varahramyan K. Nanotechnol. ,2006,17
(21) : 5319—5325
[117] Van den Berg O,Schroeter M,Capadona J R,Weder C. J.
Mater. Chem. ,2007,17(26) : 2746—2753
[118] Kim J,Yun S. Macromolecules,2006,39(12) : 4202—4206
[119] Nickerson R F,Habrle J A. Ind. Eng. Chem. ,1947,39:
1507—1512
[120] Matsumura H,Sugiyama J,Glasser W G. J. Appl. Polymer
Sci. ,2000,78(13) : 2242—2253

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Abstract

Preparation of Nanocrystalline Cellulose