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Progress in Chemistry 2010, Vol. 22 Issue (10): 2053-2059 Previous Articles   Next Articles

• Review •

Electrochromic Materials Based on Conducting Polymers

Tu Liangliang Jia Chunyang** Weng Xiaolong Deng Longjiang Tang Wu   

  1. (State key Laboratory of Electronic Thin Films and Integrated Devices, School of Microelectronics and Solid-State Electronics, University of Electronic Science and Technology of China, Chengdu 610054)
  • Received: Revised: Online: Published:
  • Contact: Jia Chunyang E-mail:cyjia@uestc.edu.cn
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Electrochromic materials have been attached more and more interests due to their potential applications such as smart windows, display and military camouflage, etc. In this paper, the electrochromic properties and research progress of polyaniline、polythiophene、polypyrrole and hybrid conducting polymers are reviewed briefly. It is believed that the conducting copolymers and organic/inorganic hybrid conducting polymers with multicolors、good stability and film formation properties should be the development direction for electrochromic materials.

Contents
1 Introduction
2 The mechanism of electrochromism
3 Electrochromic materials based on conducting polyaniline
4 Electrochromic materials based on conducting polythiophene
5 Electrochromic materials based on conducting polypyrrole
6 Electrochromic materials based on hybrid materials
6.1 Electrochromic materials based on conducting copolymers and hybrid conducting polymers with multilayers
6.2 Electrochromic materials based on organic/inorganic hybrid conducting polymers
7 Conclusions and outlook

[1 ] Thompson B C,Schottland P,Zong K,Reynolds J R. Chem.
Mater. ,2000,12(6) : 1563—1571
[2 ] Barbero C,Planes G A,Miras M C. Electrochem. Commun. ,
2001,3(3) : 113—116
[3 ] Ju W L,Sung J Y,Sun H P,Yun S U,Sung Y E. Sol. Energy
Mater. Sol. Cells,2009,93(12) : 2069—2074
[4 ] Chiang C K,Druy M A,Gau S C,Heeger A J,Louis E J,
MacDiarmid A G,Park Y W,Shirakawa H. J. Am. Chem. Soc. ,
1978,100 (3) : 1013—1015
[5 ] Bezgin B,Cihaner A M,nal A. Thin Solid Films,2008,516
(21) : 7329—7334
[6 ] Mir R M,Leon A P K M,Gordon G W. Polymer,1994,35(14) :
3113—3115
[7 ] Brabec C J,Sariciftci N S,Hummelen J C. Adv. Funct. Mater. ,
2001,11(1) : 15—26
[8 ] Roger J M. Electrochim. Acta,1999,44 (18) : 2971—2981
[9 ] Lim J Y,Ko H C,Lee H. Synth. Met. ,2006,156 ( 9 /10 ) :
695—698
[10] Mortimer R J,Dyer A L,Reynolds J R. Displays,2006,27(1) :
2—18
[11] Granqvist C G. J. Eur. Ceram. Soc. ,2005,25 ( 12 ) : 2907—
2912
[12] Biever C. New Scientist,2006,2546
[13] Granqvist C G. Handbook of Inorganic Electrochromic Materials.
Amsterdam: Elsevier. ,1995. 31—32
[14] Sian T S,Reddy G B. Sol. Energy Mater. Sol. Cells,2004,82
(3) : 375—386
[15] Somani P R,Radhakrishnan S. Mater. Chem. Phys. ,2002,77
(1) : 117—133
[16] Li Y F,Qian R Y. Electroanal. Chem. 1993,362(1 /2) : 267—
272
[17] Li Y F,Yan B Z,Yang J,Cao Y,Qian R Y. Synth. Met. ,
1988,25(1) : 79—88
[18] Louarn G,Trznadel M,Buisson J P,Laska J,Pron A,Lapkowski
M,Lefrant S. J. Phys. Chem. ,1996,100(30) : 12532—12539
[19] Brabec C J,Sariciftci N S,Hummelen J C. Adv. Funct. Mater. ,
2001,11(1) : 15—26
[20] Li D,Huang J X,Kaner R B. Acc. Chem. Res. ,2009,42(1) :
135—145
[21] Rajiv P K,Santhanam S V. J. Solid State Electrochem. ,1998,2
(2) : 123—125
[22] Gergely B, Gábor H. 26th International Spring Seminar on
Electronics Technology,2003
[23] Yang C H,Wang T L,Shieh Y T. Electrochem. Commun. ,
2009,11(2) : 335—338
[24] Subrahmanya S,Rudoif H. Chem. Mater. ,2005,17 ( 16 ) :
4078—4085
[25] Deepa M,Ahmad S,Sood K N,Alam J,Ahmad S,Srivastava A
K. Electrochim. Acta,2007,52(26) : 7453—7463
[26] Jean R. Chem. Rev. ,1992,92(4) : 711—738
[27] Argun A A,Aubert P H,Thompson B C,Schwendeman I,Gaupp
C L,Hwang J,Pinto N J,Tanner D B,MacDiarmid A G,
Reynolds J R. Chem. Mater. ,2004,16(23) : 4401—4412
[28] Gyosuke K,Katsumi Y. Synth. Met. ,2009,159(9 /10) : 914—
918
[29] Wang F,Wilson M S,Rauh R D. Macromolecules,2000,33
(6) : 2083—2091
[30] Ribeiro A S,Nogueira V C,Santos Filho P F,de Paoli M-A.
Electrochim. Acta,2004,49(14) : 2237—2242
[31] Alkan S,Cutler C A,Reynolds J R. Adv. Funct. Mater. ,2003,
13(4) : 331—336
[32] 腊明(La M) ,刘平( Liu P) ,邓文基( Deng W J) . 化学进展
(Progress in Chemistry) ,2009,21(6) : 1268—1274
[33] Sonmez G,Shen C K F,Rubin Y,Wudl F. Angew. Chem. Int.
Ed. ,2004,43(12) : 1498—1502
[34] Meng H,Tucker D,Chaffins S,et al. Adv. Mater. ,2003,15
(2) : 146—149
[35] Schwendeman I,Hickman R,Snmez G,Schottland P,Zong K,
Welsh D M,Reynolds J R. Chem. Mater. ,2002,14 ( 7 ) :
3118—3122
[36] Kumar A,Welsh D M,Morvant M C,Piroux F,Abboud K A,
Reynolds J R. Chem. Mater. ,1998,10(3) : 896—902
[37] 涂亮亮( Tu L L) ,贾春阳( Jia C Y) . 化学进展( Progress in
Chemistry) ,2010,22: 1610—1618
[38] 赵文元(Zhao W Y) ,赵文明(Zhao W M) ,王亦军(Wang Y J) .
聚合物材料的电学性能及其应用( Electric Properties and
Applications of Polymer Materials ) . 北京: 化学工业出版社
(Beijing: Chemical Industry Press) ,2006. 355—356
[39] Katsumi Y,Koji S,Gyosuke K. Synth. Met. ,2009,159(3 /4) :
188—193
[40] Gaupp C L,Zong K,Schottland P,Thompson B C,Thomas C A,
Reynolds J R. Macromolecules,2000,33(4) : 1132—1133
[41] Selin C, Abidin B, Bugra E, Baran D, Toppare L. Org.
Electron. ,2009,10(4) : 631—636
[42] Ozyurt F,Gunbas E G,Durmus A,Toppare L. Org. Electron. ,
2008,9(3) : 296—302
[43] Yasemin A U, Asuman D, Gorkem E G, Toppare L. Org.
Electron. ,2008,9(4) : 501—506
[44] Vaillant J,Monica L C,Karina C G,Casa珘n-Pastor N,Gómez-
Romero P. Prog. Solid State Chem. ,2006,34(2 /4) : 147—159
[45] Ram M K,Maccioni E,Nicolini C. Thin Solid Films,1997,303
(1 /2) : 27—33
[46] Li X G,Wang H Y,Huang M R. Macromolecules,2007,40(5) :
1489—1496
[47] Aubert P H,Argun A A,Cirpan A,Tanner D B,Reynolds J R.
Chem. Mater. ,2004,16(12) : 2386—2393
[48] Pinar C,Simge T,爦ahmetlioˇglu E,Idris M A,Cihangir T. Sol.
Energy Mater. Sol. Cells,2008,92(2) : 154—159
[49] Mitsuhiro S,Kawashita K I,Yosomiya R,Zhang G Z. Eur.
Polym. J. ,2001,37(5) : 915—919
[50] Kang J H,OhaY J,Paek S M,Hwang S J,Choy J H. Sol.
Energy Mater. Sol. Cells,2009,93(12) : 2040—2044
[51] Dean M D,Mark K,Paula T H. Chem. Mater. ,2003,15(8) :
1575—1586
[52] Dean M D,Paula T H. Chem. Mater. ,2004,16 (23) : 4799—
4805
[53] Fritz H,Marystela F,Valtencir Z,Nart F C,Torresi R M,
Oliveira O N. Chem. Mater. ,2004,16(11) : 2293—2299
[54] Chen W K,Hu C W,Hsu C Y,Ho K C. Electrochim. Acta,
2009,54(18) : 4408—4415
[55] Xia X H,Tu J P,Zhang J,Huang X H,Wang X L,Zhang W K,
Huang H. Electrochem. Commun. ,2009,11(3) : 702—705
[56] Ma L J,Li Y X,Yu X F,Yang Q B,Noh C H. Sol. Energy
Mater. Sol. Cells,2008,92(10) : 1253—1259
[57] Sonavane A C,Inamdar A I,Dalavi D S,Deshmukh H P,Patil P
S. Electrochim. Acta,2010,55(7) : 2344—2351
[58] Metin A,Burcin G,Baris K,Yagci Y,Toppare L. Polymer,
2008,49(9) : 2202—2210
[59] Tanaka A,Watanabe Y,Nagashima T,Kobayashi N. Sol. Energy
Mater. Sol. Cells,2009,93(12) : 2098—2101
[60] Heung C K,Sun A P,Lee H. Synth. Met. ,2004,143(1) : 31—
35
[61] Mahmut K,zgül H,Ceylan Z,Varlikli C,Demic S,zelik S,
Icli S. Org. Electron. ,2008,9(5) : 757—766
[62] Tung T S,Ho K C. Sol. Energy Mater. Sol. Cells,2006,90(4) :
521—537

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