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Progress in Chemistry 2010, Vol. 22 Issue (10): 2024-2032 Previous Articles   Next Articles

• Review •

 Catalysts Used in Addition Copolymerization of Ethylene and Norbornene

Yao Zhen1    Dai Bibin1    Liu Shaojie1   Cao Kun1**   Fu Jiansong2   Xie Jiaming2   

  1. (1.State Key Laboratory of Chemical Engineering, Institute of Polymerization and Polymer Engineering, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;2.Chemical Research Institute of Shanghai Petrochemical Company Limited, SINOPEC, Shanghai 200540, China)
  • Received: Revised: Online: Published:
  • Contact: Cao Kun E-mail:kcao@che.zju.edu.cn
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At present the cyclicolefin copolymer is one of the most promising alternative products with high level in the comprehensive utilization of C5 field, which has attracted more attention. The development of metallocene catalysts, non-metalocene catalysts and late transition metal catalysts used in ethylene-norbornene copolymerization are promptly reviewed. Developing new half-sandwich catalysts should be the hot spot in the field of metallocene catalysts. Half-sandwich catalysts can be further divided into two kinds, which are constrained geometry catalysts and Cp’MX3 or Cp’M(R)X2 (Cp’= cyclopentadienyl group or substituted cyclopentadienyl group; M=Ti, Zr, Hf；X= halogen or alkyl; R=OAr, NR2, NPR3). Non-metallocene catalysts have much more electrophilic metal center and more open active site, which lead to higher norbornene incorporation efficiency. In some certain conditions, it is even able to exhibit the characteristics of quasi-living polymerization. Compared to former transition metal catalysts, late transition metal catalysts should be less sensitive to oxygen and lewis acid, and owns better tolerance against the polar groups. Based on the characteristics of the copolymerization, the catalytic performance is analyzed firstly and then effect of ligand’s structure on the catalytic property. Moreover, improving the incorporation efficiency of cyclic olefin and controlling the sequence and molecular weight should be the main focus on this paper. The future research in the area has also been prospected.

Contents
1 Introduction
2 Metallocene catalysts
3 Non-metallocene catalysts
4 Late transition metal catalysts
5 Conclusions

Key words: addition copolymerization, norbornene, ethylene, metallocene catalyst, non-metalocene catalyst, late transition metal catalyst

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