中文
Announcement
More
Progress in Chemistry 2010, Vol. 22 Issue (10): 1983-1992 Previous Articles   Next Articles

• Review •

The Pollution Status and Research Progress on Organophosphate Esters Flame Retardants

Wang Xiaowei  Liu Jingfu**   Yin Yongguang   

  1. (State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China)
  • Received: Revised: Online: Published:
PDF ( 3928 ) Cited
Export

EndNote

Ris

BibTeX

With the gradually ban of brominated flame retardants, the application of organophosphate esters (OPEs) as flame retardants in various products has greatly increased in recent years. As a class of emerging pollutants, the environmental problems caused by the OPEs are more and more concerned. This article reviewed the current applications, pollution status, toxicity, and analysis methods of OPEs, with the hope of providing references for the studying of OPEs in China.

Contents
1 Introduction
2 Pollution status
2.1 OPEs in water and sediment
2.2 OPEs in gas and particle
2.3 OPEs in human body
3 Toxicities of OPEs
4 Analysis methods of OPEs
4.1 Sample pretreatment methods
4.2 OPEs detection methods 
4.3 Internal standard and blank
5 Conclusions and outlook

[1 ] Marklund A,Andersson B,Haglund P. Chemosphere,2003,53
(9) : 1137—1146
[2 ] Reemtsma T, Quintana J B, Rodil R, Garcia-Lopez M,
Rodriguez I. TrAC, Trends Anal. Chem. ,2008,27 ( 9 ) :
727—737
[3 ] Stevens R,van Es D S,Bezemer R,Kranenbarg A. Polym.
Degradation Stab. ,2006,91 (4) : 832—841
[4 ] Kannan S,Kishore K J. Chem. Eng. Data,1999,44 ( 4 ) :
649—655
[5 ] David M D,Seiber J N. Arch. Environ. Contam. Toxicol. ,
1999,36 (3) : 235—241
[6 ] Apostoluk W,Robak W. Anal. Chim. Acta,2005,548 ( 1 /
2) : 116—133
[7 ] Dodi A,Verda G. J. Chromatogr. A,2001,920 (1 /2) : 275—
281
[8 ] Lamouroux C,Virelizier H,Moulin C,Tabet J C,Jankowski C
K. Anal. Chem. ,2000,72 (6) : 1186—1191
[9 ] European Flame Retardants Association. [2009-10 ],http: / /
www. cefic-efra. com / content /Default. asp? PageID = 100
[10] 王玮( Wang W) . [2009-10 ], http: / /www. chemindustry.
com. cn /Untitled-1. html
[11] Mabey W,Mill T. J. Phys. Chem. Ref. Data,1978,7 ( 2 ) :
383—415
[12] Aubert S D,Li Y,Raushel F M. Biochemistry (Mosc) . 2004,
43 (19) : 5707—5715
[13] Iche-Tarrat N,Barthelat J C,Rinaldi D,Vigroux A. The Journal
of Physical Chemistry B,2005,109 (47) : 22570—22580
[14] Reemtsma T,Weiss S,Mueller J,Petrovic M,Gonzalez S,
Barcelo D,Ventura F,Knepper T P. Environ. Sci. Technol. ,
2006,40 (17) : 5451—5458
[15] Meyer J,Bester K J. Environ. Monit. ,2004,6 (7) : 599—605
[16] Rodil R,Quintana J B,Reemtsma T. Anal. Chem. ,2005,77
(10) : 3083—3089
[17] Bester K J. Environ. Monit. ,2005,7 (5) : 509—513
[18] Quintana J B,Rodil R,Reemtsma T. Anal. Chem. ,2006,78
(5) : 1644—1650
[19] Marklund A, Andersson B, Haglund P. Environ. Sci.
Technol. ,2005,39 (19) : 7423—7429
[20] Rodil R,Quintana J B,Lopez-Mahia P,Muniategui-Lorenzo S,
Prada-Rodriguez D. J. Chromatogr. A,2009,1216 ( 14 ) :
2958—2969
[21] Martinez-Carballo E,Gonzalez-Barreiro C,Sitka A,Scharf S,
Gans O. Sci. Total Environ. ,2007,388: 290—299
[22] Kim S D,Cho J,Kim I S,Vanderford B J,Snyder S A. Water
Res. ,2007,41 (5) : 1013—1021
[23] Fries E,Puttmann W J. Environ. Monit. ,2003,5 (2) : 346—
352
[24] Fries E,Puttmann W J. Environ. Monit. ,2001,3 (6) : 621—
626
[25] Cho K J,Hirakawa T,Mukai T,Takimoto K,Okada M. Water
Res. ,1996,30 (6) : 1431—1438
[26] Paxeus N. Water Sci. Technol. ,2000,42 (7 /8) : 323—333
[27] Kawagoshi Y,Nakamura S,Fukunaga I. Chemosphere,2002,
48 (2) : 219—225
[28] Andresen J A,Grundmann A,Bester K. Sci. Total Environ. ,
2004,332 (1 /3) : 155—166
[29] Andresen J,Bester K. Water Res. ,2006,40 (3) : 621—629
[30] Regnery J,Puttmann W. Clean-Soil Air Water,2009,37 ( 4 /
5) : 334—342
[31] Bacaloni A, Cucci F, Guarino C, Nazzari M, Samperi R,
Lagana A. Environ. Sci. Technol. ,2008,42 ( 6 ) : 1898—
1903
[32] Chung H W,Ding W H. Anal. Bioanal. Chem. ,2009,395
(7) : 2325—2334
[33] Garcia-Lopez M, Rodriguez I, Cela R. Anal. Chim. Acta,
2008,625 (2) : 145—153
[34] Stackelberg P E, Furlong E T, Meyer M T, Zaugg S D,
Henderson A K,Reissman D. B. Sci. Total Environ. ,2004,
329 (1 /3) : 99—113
[35] Carlsson H,Nilsson U,Becker G,Ostman C. Environmental
Science & Technology,1997,31 (10) : 2931—2936
[36] Solbu K,Thorud S,Hersson M,vreb S,Ellingsen D G,
Lundanes E,Molander P. J. Chromatogr. A,2007,1161 ( 1 /
2) : 275—283
[37] Carlsson H,Nilsson U,Ostman C. Environ. Sci. Technol. ,
2000,34 (18) : 3885—3889
[38] Ingerowski G,Friedle A,Thumulla J. Indoor Air,2001,11
(3) : 145—149
[39] García M,Rodríguez I,Cela R. J. Chromatogr. A,2007,1152
(1 /2) : 280—286
[40] García M,Rodríguez I,Cela R. Anal. Chim. Acta,2007,590
(1) : 17—25
[41] Staaf T,Ostman C J. Environ. Monit. ,2005,7 ( 4 ) : 344—
348
[42] Staaf T,Ostman C J. Environ. Monit. ,2005,7 ( 9 ) : 883—
887
[43] Saito I,Onuki A,Seto H. Indoor Air,2007,17 (1) : 28—36
[44] Hartmann P C,Bürgi D,Giger W. Chemosphere,2004,57
(8) : 781—787
[45] Makinen M S E,Makinen M R A,Koistinen J T B,Pasanen A
L,Pasanen P O,Kalliokoski P I,Korpi A M. Environ. Sci.Technol. ,2009,43 (3) : 941—947
[46] Stapleton H M,Klosterhaus S,Eagle S,Fuh J,Meeker J D,
Blum A,Webster T F. Environ. Sci. Technol. ,2009,43
(19) : 7490—7495
[47] Wensing M, Uhde E, Salthammer T. Sci. Total Environ. ,
2005,339 (1 /3) : 19—40
[48] Ciccioli P,Cecinato A,Brancaleoni E,Montagnoli M,Allegrini
I. Int. J. Environ. Anal. Chem. ,1994,55 (1 /4) : 47—59
[49] Aston L S,Noda J,Seiber J N,Reece C A. Bul. Environ.
Contam. Toxicol. ,1996,57 (6) : 859—866
[50] Laniewski K,BorEn H,Grimvall A. Environ. Sci. Technol. ,
1998,32 (24) : 3935—3940
[51] Marklund A, Andersson B, Haglund P. Environ. Sci.
Technol. ,2005,39 (10) : 3555—3562
[52] Tollbck J, Tamburro D, Crescenzi C, Carlsson H. J.
Chromatogr. A,2006,1129 (1) : 1—8
[53] Hughes M F,Edwards B C,Mitchell C T,Bhooshan B. Food
Chem. Toxicol. ,2001,39 (12) : 1263—1270
[54] Meeker J D,Stapleton H M. Environ. Health Perspect. ,2009:
117(10) : 1587—1592
[55] Schindler B K,Foerster K,Angerer J. J. Chromatogr. B,2009,
877 (4) : 375—381
[56] Schindler B K,Forster K,Angerer J. Anal. Bioanal. Chem. ,
2009,395 (4) : 1167—1171
[57] Jonsson O B,Dyremark E,Nilsson U L. J. Chromatogr. B,
2001,755 (1 /2) : 157—164
[58] Jonsson O,Nilsson U. Anal. Bioanal. Chem. ,2003,377 (1) :
182—188
[59] Jonsson O B,Nilsson U L. J. Sep. Sci. ,2003,26 ( 9 /10 ) :
886—892
[60] Amini N,Crescenzi C. J. Chromatogr. B,2003,795 ( 2 ) :
245—256
[61] Shah M,Meija J,Cabovska B,Caruso J A. J. Chromatogr. A,
2006,1103 (2) : 329—336
[62] Matthews H B,Dixon D,Herr D W,Tilson H. Toxicol. Ind.
Health,1990,6 (1) : 1—15
[63] Matthews H B, Eustis S L, Haseman J. Fundam. Appl.
Toxicol. ,1993,20 (4) : 477—485
[64] Tilson H A,Veronesi B,McLamb R L,Matthews H B. Toxicol.
Appl. Pharmacol. ,1990,106 (2) : 254—269
[65] Umezu T,Yonemoto J, Soma Y, Suzuki T. Toxicol. Appl.
Pharmacol. ,1998,148 (1) : 109—116
[66] Saboori A M, Lang D M, Newcombe D S. Chem. Biol.
Interact. ,1991,80 (3) : 327—338
[67] Latendresse J R,Azhar S,Brooks C L,Capen C C. Toxicol.
Appl. Pharmacol. ,1993,122 (2) : 281—289
[68] Latendresse J R,Brooks C L,Capen C C. Toxicol. Pathol. ,
1994,22 (4) : 341—352
[69] Latendresse J R,Brooks C L,Flemming C D,Capen C C.
Fundam. Appl. Toxicol. ,1994,22 (3) : 392—399
[70] Lin K. Environmental Chemistry Letters,2009,7 (4): 309—312
[71] Quintana J B, Rodil R, Reemtsma T, Garcia-Lopez M,
Rodriguez I. TrAC,Trends Anal. Chem. ,2008,27 ( 10 ) :
904—915
[72] Knepper T P,Sacher F,Lange F T,Brauch H J,Karrenbrock
F,Roerden O,Lindner K. Waste Manage. ,1999,19 ( 2 ) :
77—99
[73] Bacaloni A,Cavaliere C,Foglia P,Nazzari M, Samperi R,
Lagana A. Rapid Commun. Mass Spectrom. ,2007,21 ( 7 ) :
1123—1130
[74] Rodríguez I,Calvo F,Quintana J B,Rubí E,Rodil R,Cela R.
J. Chromatogr. A,2006,1108 (2) : 158—165
[75] Quintana J B,Reemtsma T. J. Chromatogr. A,2006,1124 (1 /
2) : 22—28
[76] Garcia-Lopez M, Rodriguez I, Cela R. Journal of
Chromatography A,2007,1166 (1 /2) : 9—15
[77] Mller K,Crescenzi C, Nilsson U. Anal. Bioanal. Chem. ,
2004,378 (1) : 197—204
[78] Sjodin A,Carlsson H A,Thuresson K,Sjolin S,Bergman A,
Ostman C. Environmental Science & Technology, 2000, 35
(3) : 448—454
[79] Otake T,Yoshinaga J,Yanagisawa Y. Environ. Sci. Technol. ,
2001,35 (15) : 3099—3102
[80] Toda H,Sako K,Yagome Y,Nakamura T. Anal. Chim. Acta,
2004,519 (2) : 213—218
[81] Marklund A,Andersson B,Haglund P. J. Environ. Monit. ,
2005,7 (8) : 814—819
[82] Bjrklund J, Isetun S, Nilsson U. Rapid Commun. Mass
Spectrom. ,2004,18 (24) : 3079—3083
[83] Yoshida T,Matsunaga I,Oda H. J. Chromatogr. A,2004,
1023 (2) : 255—269
[84] Sanchez C,Ericsson M,Carlsson H,Colmsj A. J. Chromatogr.
A,2003,993 (1 /2) : 103—110
[85] Ericsson M,Colmsjo A. Anal. Chem. ,2003,75 (7) : 1713—
1719
[86] Isetun S,Nilsson U,Colmsj A. Anal. Bioanal. Chem. ,2004,
380 (2) : 319—324
[87] Isetun S,Nilsson U,Colmsj A,Johansson R. Anal. Bioanal.
Chem. ,2004,378 (7) : 1847—1853
[88] Isetun S,Nilsson U. The Analyst,2005,130 (1) : 94—98
[89] Quintana J,Rodil R,López-Mahía P,Muniategui-Lorenzo S,
Prada-Rodríguez D. Anal. Bioanal. Chem. ,2007,388 ( 5 ) :
1283—1293
[90] García-López M, Rodríguez I, Cela R. J. Chromatogr. A,
2009,1216 (42) : 6986—6993
[91] Nagase M,Toba M,Kondo H,Yasuhara A,Hasebe K. Anal.
Sci. ,2003,19 (12) : 1617—1620
[92] Rodil R,Quintana J B,Reemtsma T. Anal. Chem. ,2005,77
(10) : 3083—3089
[93] Moller K,Nilsson U,Crescenzi C. J. Chromatogr. A,2001,
938 (1 /2) : 121—130
[94] Moller K,Crescenzi C, Nilsson U. Anal. Bioanal. Chem. ,
2004,378 (1) : 197—204

[1] Jin Zhou, Pengpeng Chen. Modification of 2D Nanomaterials and Their Applications in Environment Pollution Treatment [J]. Progress in Chemistry, 2022, 34(6): 1414-1430.
[2] Benzhan Zhu, Jing Zhang, Miao Tang, Chunhua Huang, Jie Shao. Mechanism Investigation on DNA Damage Induced by Carcinogenic Haloquinoid Disinfection Byproducts [J]. Progress in Chemistry, 2022, 34(1): 227-236.
[3] Yuzhu Zhang, Jing Zhan, Qian S. Liu, Qunfang Zhou, Guibin Jiang. Neurotoxicity Induced by Atmospheric Fine Particulate Matters and the Underlying Molecular Mechanism [J]. Progress in Chemistry, 2021, 33(5): 713-725.
[4] Bingjie Zhang, Qian S. Liu, Qunfang Zhou, Jianqing Zhang, Guibin Jiang. Neurotoxicological Effects of Nanosilver [J]. Progress in Chemistry, 2018, 30(9): 1392-1402.
[5] Yawei Wang, Ying Wang, Guibin Jiang. Analytical Methods, Environmental Pollutions and Toxicity of Short Chain Chlorinated Paraffins [J]. Progress in Chemistry, 2017, 29(9): 919-929.
[6] Li Zhongmin, Guo Lianghong. Environmental Occurrence and Toxicology of Fluorotelomer Alcohols [J]. Progress in Chemistry, 2016, 28(7): 993-1005.
[7] Xiang Lei, Sun Teng-Fei, Mo Ce-Hui, Li Yan-Wen, Cai Quan-Ying, Li Hui. Related Environmental Problems and Research Progresses of Quaternary Ammonium Compounds (QACs) [J]. Progress in Chemistry, 2016, 28(5): 727-736.
[8] Liu Guorui, Li Li, Sun Sufang, Jiang Xiaoxu, Wang Mei, Zheng Minghui. Sources, Analytical Methods and Environmental Characteristics of Polybrominated Biphenyls [J]. Progress in Chemistry, 2014, 26(08): 1434-1444.
[9] Shi Yali, Cai Yaqi. Study of Per- and Polyfluoroalkyl Substances Related Environmental Problems [J]. Progress in Chemistry, 2014, 26(04): 665-681.
[10] Li Yang, Niu Junfeng, Zhang Chi, Wang Zhengzao, Zheng Mengyuan, Shang Enxiang. Photoinduced Toxic Mechanism of Metallic Nanoparticles toward Bacteria in Water [J]. Progress in Chemistry, 2014, 26(0203): 436-449.
[11] Wu Yiping, Guo Lianghong. Photoelectrochemical Sensors for the Detection of DNA Damage [J]. Progress in Chemistry, 2014, 26(01): 1-9.
[12] Lv Jitao, Zhang Shuzhen*. Interactions Between Manufactured Nanomaterials and Plants: Phytotoxicity, Uptake and Translocation [J]. Progress in Chemistry, 2013, 25(01): 156-163.
[13] Li Zhuona, Zhou Qunfang, Liu Jiyan, Shi Yali, Cai Yaqi, Jiang Guibin. Environmental Behavior and Toxicological Effects of Polycyclic Musks [J]. Progress in Chemistry, 2012, 24(04): 606-615.
[14] Jiang Guoxiang, Shen Zhenyao, Niu Junfeng, Zhuang Lingping, He Tiande. Nanotoxicity of Engineered Nanomaterials in the Environment [J]. Progress in Chemistry, 2011, 23(8): 1769-1781.
[15] Zhang Zhiyong, Zhao Yuliang, Chai Zhifang. Radioanalytical Methods in Nanotoxicology Studies [J]. Progress in Chemistry, 2011, 23(7): 1527-1533.