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Progress in Chemistry 2010, Vol. 22 Issue (10): 1940-1951 Previous Articles   Next Articles

• Review •

Application of Organic Macrocyclic Supramolecular Structures on Adsorption and Conversion of Carbon Dioxide

Li Peipei   Liu Li**   

  1. (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China)
  • Received: Revised: Online: Published:
  • Contact: Li Liu E-mail:lliu@dicp.ac.cn
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Adsorption and conversion of carbon dioxide has called attention worldwidely not only due to the increasing environmental concerns, but also in view of the carbon resource utilization. The research progress on the physical adsorption and chemical conversion of carbon dioxide using organic macrocyclic supramolecular host structures, such as crown ether, cyclodextrin, calixarene and cucurbituril has been overviewed. With intrinsic cavity structure, the organic macrocyclic supramolecular hosts can further form porous materials through self-assembly. On one hand, selective adsorption and separation of carbon dioxide by the organic macrocyclic supramolecular hosts, their derivatives and porous self-assembly materials with specific size and versatile shape is reviewed. On the other hand, the chemical conversion of carbon dioxide involves the reactions with amines, epoxides, alcohols and phenates in the presence of organic macrocyclic supramolecular host structures which act as reactants, catalysts or cocatalysts. These chemical transformations of carbon dioxide enable the utilization of carbon resource and the preparation of functional materials. The review demonstrates the unique applications of molecular recognition and assembly characteristics of organic macrocyclic supramolecular structures on the adsorption and conversion of carbon dioxide. What is more, the outlook of the research area is also provided.

Contents
1 Introduction
2 Adsorption of CO2 by organic macrocyclic supramolecular structures
2.1 Adsorption of CO2 by crown ether
2.2 Adsorption of CO2 by cyclodextrin
2.3 Adsorption of CO2 by calixarene
2.4 Adsorption of CO2 by cucurbituril
3 Chemical conversion of CO2 in the presence of organic macrocyclic supramolecular structures
3.1 Reaction of CO2 with amines
3.2 Reaction of CO2 with epoxides
3.3 Reaction of CO2 with alcohols
3.4 Reaction of CO2 with phenates
4 Conclusions and outlook

Key words: supramolecule, assembly, carbon dioxide, adsorption, conversion

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