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Progress in Chemistry 2010, Vol. 22 Issue (10): 1882-1900 Previous Articles   Next Articles

• Review •

Reaction and Mechanism of Low-Temperature Selective Catalytic Reduction of NOx by NH3 over Manganese Oxide-based Catalysts

Sun Liang1,2   Xu Youjia2   Cao Qingqing2   Hu Bingqing2   Wang Chao2   Jing Guohua1* *   

  1. (1. College of Chemical Engineering, Huaqiao University, Xiamen 361021, China; 2. Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China)
  • Received: Revised: Online: Published:
  • Contact: Jing Guohua E-mail:zhoujing@hqu.edu.cn
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More attention to manganese oxide-based catalysts has been paid due to their excellent catalytic activities in low-temperature selective catalytic reduction of NOx by NH3 (NH3-SCR) in recent years. The progress of low-temperature NH3-SCR on manganese oxide-based catalysts is reviewed in this paper. The effects of oxidation states, bulk and surface structures of manganese oxides together with the nature of the doping cations and the supports on catalytic activities are extensively analyzed, and according to these results, the general conclusions can be drawn that both higher oxidation state of manganese and higher surface areas favor for the reaction of NH3-SCR at low temperatures, the doping cations such as Ce4+, Cr3+, Fe3+, Cu2+ and Sn4+ can enhance NOx conversion and/or N2 selectivity of manganese oxide-based catalysts in low-temperature NH3-SCR, and the supports with excellent features like TiO2 and silicon-aluminum zeolites can facilitate the improvements of hydrophobic ability and sulfur-resistant performance. Meanwhile, the mechanisms of low-temperature NH3-SCR according to activations of NH3 and NO alone or both are systematically discussed, and depending on the reaction conditions, Eley-Rideal and Langmuir-Hinshelwood mechanisms as well as Mars-van Krevelen one possibly simultaneously occur in low-temperature NH3-SCR reactions over manganese oxide-based catalysts. Finally, the general proposal for developing high active manganese oxide-based catalysts in low-temperature NH3-SCR is put forward.

Contents
1. Introduction
2. Manganese oxide-based catalysts for low-temperature NH3-SCR
2.1 Unsupported manganese oxide-based catalysts
2.2 Supported manganese oxide-based catalysts
3. Mechanisms of low-temperature NH3-SCR on manganese oxide-based catalysts
3.1 Eley-Rideal mechanism
3.2 Langmuir-Hinshelwood mechanism
4. Conclusions and prospect

Key words: nitrogen oxides, NH3-SCR, manganese oxides, reaction mechanism, hydrophobicity

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