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Progress in Chemistry 2010, Vol. 22 Issue (09): 1836-1843 Previous Articles   Next Articles

• Review •

Catalytic Decomposition of PCDD/Fs from Flue Gas

Tian Bo   Huang Jun   Deng Shubo   Yang Shuwei   Yu Gang**   

  1. (POPs Research Centre, Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China)
  • Received: Revised: Online: Published:
  • Contact: Yu Gang E-mail:yg-den@tsinghua.edu.cn
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The catalytic decomposition is one of the effective end-pipe technologies for PCDD/Fs removal from flue gas under mild conditions, which is on the basis of catalytic reduction and oxidation process. So far, the catalysts researched in lab-scale are mainly two categories: noble metal (Pt, Pb, Lr, etc.) and transition metal (V, Cr, W, etc.) oxides. In the field application, the selective catalytic reduction (SCR) with V2O5/W(Mo)O3-TiO2 as the catalyst is the most popular techniques, which can remove PCDD/Fs and NOx simultaneously. This paper reviews the wide scale of the catalytic decomposition of PCDD/Fs by noble metals and transition metal oxides. The destruction principles of PCDD/Fs by these two series of catalysts are introduced. The effects of the reaction conditions on the destruction efficiency are discussed such as catalysts and supports, temperature, H2O vapor, space velocity (SV) and the co-pollutants in the flue gas. Furthermore, the advantages and limitations of the destruction for PCDD/Fs by SCR are evaluated as well as the deactivation and poisoning of catalysts in situ applications. Based on the requirements of industrial application for PCDD/Fs and NOx removal, the research trends of SCR for the future are proposed in order to further improve the destruction efficiency and cost conservation.

Contents
1 Introduction
2 Decomposition of PCDD/Fs by Noble metals
2.1 Reaction Mechanism
2.2 Research progress
3 Decomposition of PCDD/Fs by Metal oxides
3.1 Reaction Mechanism
3.2 Research progress
4 Decomposition of PCDD/Fs by Selective catalytic reduction (SCR)
4.1 Application progress
4.2 Application conditions
4.3 Deactivation and regeneration of SCR catalysts
5 Conclusions and prospects

Key words: PCDD/Fs, flue gas, catalytic decomposition, noble metal, metal oxide, selective catalytic reduction(SCR)

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