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Progress in Chemistry 2010, Vol. 22 Issue (09): 1799-1807 Previous Articles   Next Articles

• Review •

Synthesis of Well-Defined Polymers via Mechanism Transformation between Living Ring-Opening Polymerization and Controlled Free Radical Polymerization

Zhou Lilin   Yuan Jinying**   Cai Zhinan  Hong Xiaoyin   

  1. (Key Laboratory of Organic Optoelectronics and Molecular Engineering of the Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China)
  • Received: Revised: Online: Published:
  • Contact: Yuan Jinying E-mail:yuanjy@mail.tsinghua.edu.cn
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Controlled radical polymerization and living ring-opening polymerization can be combined by mechanism transformation to synthesize various copolymers with novel well-defined macromolecular architectures. This method has received much attention. This article summarizes recent research progress on the preparation of well-defined copolymers by mechanism transformation between controlled radical polymerizations, including atom transfer radical polymerization (ATRP), reversible addition–fragmentation transfer (RAFT) polymerization, and stable free-radical polymerization (SFRP), with living ring-opening polymerization.

Contents 
1 Introduction
2 Mechanism transformation from controlled free radical polymerization to living ring-opening polymerization
2.1 Mechanism transformation from ATRP to ROP
2.2 Mechanism transformation from RAFT to ROP
3. Mechanism transformation from ROP to controlled free radical polymerization
4. Double functional initiator
4.1 Double functional initiator for ATRP and ROP
4.2 Double functional initiator for RAFT and ROP
4.3 Double functional initiator for SFRP and ROP
5. Conclusions and outlook

Key words: living ring-opening polymerization, controlled free radical polymerization, mechanism transformation, ATRP, RAFT, SFRP

CLC Number: 

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