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Progress in Chemistry 2010, Vol. 22 Issue (09): 1741-1752 Previous Articles   Next Articles

• Review •

Fluorescent Probes for Mercury Ion Based on Small Molecules

Shi Huifang1   Zhao Qiang1,2  An Zhongfu1  Xu Wenjuan1  Liu Shujuan1** Huang Wei1**   

  1. (1.Nanjing University of Posts & Telecommunications (NUPT), Institute of Advanced Materials (IAM),  Key Lab for Organic Electronics & Information Displays, Nanjing , 210003，China; 2.Nanjing University, State Key Laboratory of Coordination Chemistry, Nanjing, 210093, China )
  • Received: Revised: Online: Published:
  • Contact: Huang Wei E-mail:iamwhuang@njupt.edu.cn
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As one of the most toxic heavy metals, mercury ion causes severe environmental and healthy problems. Hence, its sensing methods have been widely studied. Due to their unique advantages, such as high sensitivity, low cost and fast detection, fluorescent probes have been one of the most important sensing methods of mercury ion. The mercury ion could be coordinated with specific receptors of fluorescent probes. Such complexation causes the changes of photophysical properties and realizes highly selective mercury ion detection. Herein, fluorescent probes for mercury ion based on small molecules reported in recent years have been reviewed. The design principles of probe materials, as well as their sensing mechanisms and applications are summarized. The structure-property relationships are also elucidated. Finally, the development and prospect are foreseen in the field of mercury ion probes.

Contents
1. Introduction
2. Design principles
3. The progress of fluorescent probes on mercury ion
3.1 Turn-off  fluorescent probes on mercury ion
3.2 Turn-on  fluorescent probes on mercury ion
3.3 Radiometric  fluorescent probes on mercury ion
4. Conclusion and outlook

Key words: mercury Ion, fluorescent probes, Ion-recognition

CLC Number: 

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