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Progress in Chemistry 2010, Vol. 22 Issue (09): 1709-1719 Previous Articles   Next Articles

• Review •

3d-4f Single Molecule-Magnets

Zhang Xuhong**   Wang Shuping   

  1. (College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, China)
  • Received: Revised: Online: Published:
  • Contact: Zhang Xuhong E-mail:xuhongshd@126.com
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Single-molecule magnets (SMMs) are molecules that can be magnetized in a magnetic field and retain the magnetization when the external field is switched off. It is currently stimulating abundant research in relation to potential applications in information processing and storage. In this paper, the advantages of 3d-4f single molecule-magnets are discussed. The synthesis strategies and magnetic properties of 3d-4f SMMs are reviewed. Factors affecting the magnetic properties of 3d-4f SMMs are summarized.

Contents:
1 Introduction
2 Advantages of 3d-4f Single molecule-magnets
3 Synthetic strategies and magnetic properties of 3d-4f Single Molecule-Magnets
3.1 Synthetic strategies of 3d-4f SMMs
3.2 Magnetic properties of 3d-4f SMMs
4. Factors affecting the magnetic properties of 3d-4f SMMs
4.1 Effect of metal ions
4.2 Effect of Ligands
5 Conclusion and Outlook

Key words: single-molecular magnet, lanthanides, magnetic properties, anisotropy, quantum tunneling of magnetization

CLC Number: 

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Abstract

3d-4f Single Molecule-Magnets