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Progress in Chemistry 2010, Vol. 22 Issue (09): 1701-1708 Previous Articles   Next Articles

• Review •

Preparation and Catalytic Performance of the Transition Metal Phosphides

Liu Lihua  Li Guangci   Liu Di   Liu Yunqi   Liu Chenguang**   

  1. (State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis of CNPC, China University of Petroleum, Qingdao 266555, China )
  • Received: Revised: Online: Published:
  • Contact: Liu Chenguang E-mail:cgliu@upc.edu.cn
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The diminishing quality of oil feedstocks coupled with increasingly more stringent environmental regulations limiting the content of sulfur in transportation fuels have given rise to a need for improved hydroprocessing technology. Transition metal phosphides have attracted attention not only because they have excellent reaction catalytic selectivity for deep hydrodesulfurization and hydrodenitrogenation, but also because they are much more stable than metal carbides and nitrides with regard to hydrogen sul?de. The present article intends to review recent progress in the fabrication, catalytic performance and active phase of transition metal phosphides. A surface phosphosul?de phase may be formed while the bulk structure of the phosphides is retained under hydrodesulfurization reaction conditions. The surface phosphosul?de phase may be responsible for the high and stable activity of the phosphide catalyst. These phosphide based catalysts are becoming an interesting and promising replacement for the traditional bimetallic systems such as Mo or W sul?de catalysts promoted with Ni or Co in this type of reaction. This approach provides considerable economical advantages as well as enhanced catalyst life times and higher activity. Contents 1 Introduction 2 The synthetic methods of the transition metal phosphides 2.1 The transition metal phosphides prepared by the hydrothermal method 2.2 The transition metal phosphides prepared by the temperature-programmed reduction 2.3 The transition metal phosphides prepared by the decomposition of hypophosphite precursor 3 The catalytic performance of the transition metal phosphides 4 Summary and perspective

Key words: transition metal phosphide, preparation, hydrodesul furization, hydrodenitrogenation, active phase

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