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Progress in Chemistry 2010, Vol. 22 Issue (08): 1672-1678 Previous Articles   

• Review •

In-situ Passive Sampling Techniques

Fan Hongtao1,2  Sui Dianpeng2  Chen Hong2  Dong Jia2  Zang Shuyan1  Sun Ting2**   

  1. (1. College of Applied Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142, China; 2. Department of Chemistry, Northeastern University, Shenyang 110004, China)
  • Received: Revised: Online: Published:
  • Contact: Sun Ting E-mail:sun1th@neu.edu.cn
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In this paper, three in-situ passive sampling techniques and devices, including dialysis peepers, diffusive equilibrium in thin-films (DET) technique and diffusive gradients in thin-films (DGT) technique,  are introduced. The principles, devices, advantages of three in-situ passive sampling techniques are summarized. The applications of three techniques of three in-situ passive sampling techniques, including the in situ sampling of total dissovled concentrations of heavy metals in water and sediment porewaters by dialysis peepers and DET coupled with DGT technique, and the prediction of bioavailability of heavy metals and its speciation measurement with DGT techniques, are focused. Comparison with the soil chemical extraction method, DGT can be used as a new method for the measurement of bioavailability of heavy metals. The speciation of heavy metals can be measured by DGT coupled with other techniques( e.g. DET, ion selective electrode, competing ligand exchange and HPLC-ICP-MS methods ). The prospects of in-situ passive sampling technique are also assessed. 


Contents 
1. Introduction 
2. Dialysis peeper technique 
3. Diffusive equilibrium in thin-films technique 
4. Diffusive gradients in thin-films technique 
5. Applications 
5.1 Application of dialysis peeper 
5.2 Application of diffusive equilibrium in thin-films technique
5.3 Application of diffusive gradients in thin-films technique
6. Outlook

Key words: In-situ passive sampling techniques, Dialysis peepers, Diffusive equilibrium in thin-films, Diffusive gradients in thin-films, heavy metal

CLC Number: 

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Abstract

In-situ Passive Sampling Techniques