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Progress in Chemistry 2010, Vol. 22 Issue (07): 1471-1481 Previous Articles   Next Articles

• Invited Article •

Recent Progress in Self-Supported Chiral Catalysts

Wang Haiming    Wang Zheng    Ding Kuiling**   

  1. (State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032, China)
  • Received: Online: Published:
  • Contact: Ding Kuiling E-mail:kding@mail.sioc.ac.cn
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The immobilization of homogeneous catalysts for recycle and reuse provides an effective way to solve the problems associated with the catalyst cost and metal contamination in a homogeneous catalytic process. Different from the conventional catalyst immobilization methods, the self-supporting strategy utilizes homochiral metal-organic coordination polymers generated by self-assembly of chiral multitopic ligands with metal ions without using any support. The self-supported chiral catalysts as a novel immobilization of homogeneous catalysts strategy demonstrated excellent enantioselectivities in heterogeneous catalysis of a variety of asymmetric reactions. This paper reviews the progress in the research on a variety of heterogeneous asymmetric catalytic reactions with self-supported chiral catalysts.

Contents 
1 Introduction 
2 The concept of the “self-supporting” strategy 
3 Homochiral self-supported catalysts (type Ⅰ) in heterogeneous asymmetric ractions 
3.1 Asymmetric carbon-carbon bond-forming reactions 
3.2 Enantioselective oxidations 
3.3 Enantioselective hydrogenations 
4 Pendant auxiliaries on self-supported catalysts (Type Ⅱ) in heterogeneous asymmetric ractions 
4.1 Asymmetric carbon-carbon bond-forming reactions
4.2 Enantioselective oxidations 
4.3 Enantioselective hydrogenations 
5 Conclusions and outlook

Key words: self-supported catalyst, heterogeneous catalysts, asymmetric catalysis, chirality, recycle and reuse

CLC Number: 

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