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Progress in Chemistry 2010, Vol. 22 Issue (07): 1286-1294 Previous Articles   Next Articles

• Invited Article •

Catalytic Organic Reactions in CO2/H2O Medium

Wu Suxiang    Fan Honglei    Cheng Yan    Wang Qian    Han Buxing**   

  1. ( Institute of Chemistry Chinese Academy of Science, Beijing 100190, China )
  • Received: Online: Published:
  • Contact: Han Buxing E-mail:hanbx@iccas.ac.cn
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Green chemistry is the trend of chemistry in the future. Utilization of green solvents effectively is one of the important topic in green chemistry. CO2/H2O is green reaction medium of some unique features, and can be used in different chemical reactions. Especially, it can be used in the reactions catalyzed by weak acids, in which use of conventional acids can be avoided. In this review, we first discuss the variation of the acidity CO2/H2O system with temperature and pressure, then some chemical reactions in CO2/H2O system are discussed, including dehydration reaction, alkylation reaction, citronellal cyclization reaction,diazonium reaction, conversion of polyalcohol to cyclic ether, oxybromination reaction, selective reduction of nitroarenes, polysaccharide hydrolysis, conversion of biomass, hydrolysis of propylene oxide, decarboxylation reaction, oxidation of alcohols, enantioselective sulfoxidation, asymmetric reduction of ketones. Finallly, the future directions for the application of CO2/H2O system in chemical reaction are discussed briefly.

Contents 
1 Introduction 
2 Acidity changes in CO2/H2O 
3 Chemical reactions in CO2/H2O 
3.1 Dehydration reaction and alkylation reaction 
3.2 Citronellal cyclization reaction 
3.3 Diazonium reaction 
3.4 Coversation of polyalcohol to cyclic ether 
3.5 Oybromination reaction 
3.6 Selective reduction of nitroarenes 
3.7 Polysaccharide hydrolysis 
3.8 Conversation of biomass and hydrolysis of propylene oxide 
3.9 Decarboxylation reaction
3.10 Oxidation of alcohols 
3.11 Enantioselective sulfoxidation 
3.12 Asymmetric reduction of ketones 
4 Conclusions and outlook

Key words: green chemistry, mixed green solvents, CO2, H2O, catalysis, organic reaction

CLC Number: 

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