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Progress in Chemistry 2010, Vol. 22 Issue (06): 1185-1194 Previous Articles   Next Articles

• Invited Article •

Application of ATR-FTIR spectroscopy in the study of adsorption on environmental micro-interfaces

Yang Xiaofang1,2; Wang Dongsheng1*; Sun Zhongxi3;  Liu Huijuan1; Allan Holmgren2   

  1. (1. Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China 2. Department of Chemical Engineering and Geosciences, Luleå University of Technology, Luleå SE-97187, Sweden 3. Department of Chemistry and Chemical Engineering, Jinan University, Jinan 250022, China)
  • Received: Revised: Online: Published:
  • Contact: Wang Dongsheng E-mail:wgds@rcees.ac.cn
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Interfacial adsorption process is the initial step or key step for most of environmental micro-interface reactions. The online study of environmental micro-interfacial adsorption by in situ research methods provides direct information about interface reactions and reliable evidence for the detection of reaction mechanisms which are of great importance to understand the rule of transformation and distribution of pollutants in the environment. Because of its unique sampling principle, convenient sample pre-treatment and wide applicability, attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR) is becoming a powerful tool for investigating the interface reactions. Based on a brief introduction of the working principle of ATR-FTIR, the application of this technique in the investigation of adsorption on environmental interfaces, especially mineral-water interfaces, was summarized. Furthermore, the perspective of this method was discussed as well.

Contents
1 Introduction
2 ATR-FTIR spectroscopy
2.1 The principle of ATR-FTIR spectroscopy
2.2 Sampling methods and ATR accessory
3 Application of ATR-FTIR in the study of adsorption on the environmental micro-interfaces
3.1 Adsorption of inorganic anions
3.2 Adsorption of carboxylates
3.3 Adsorption of organic pollutants
3.4 Catalytic reaction on solid-liquid interfaces
4 Conclusion

Key words: environmental micro-interface, mineral, adsorption, ATR-FTIR

CLC Number: 

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