中文
Earlier issues
Announcement
More
Progress in Chemistry 2010, Vol. 22 Issue (06): 1044-1057 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Invited Article •

Electrochemical Impedance Spectroscopy in Lithium ion Batteries Diagnosis

Zhuang Quanchao1**; Xu Shoudong1; Qiu Xiangyun1; Cui Yongli1; Fang Liang1; Sun Shigang2**   

  1. (1. School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, China; 2. State Key Lab for Physical Chemistry of Solid Surfaces, Department of Chemistry, Xiamen University, Xiamen 361005 , China)
  • Received: Revised: Online: Published:
  • Contact: Zhuang QuanChao E-mail:zhuangquanchao@126.com
  • Supported by:

    National Basic Research Program of China

PDF ( 11265 ) Cited
Export

EndNote

Ris

BibTeX

Electrochemical impedance spectroscopy, or EIS, is one of the most powerful tools to analyze electrochemical processes occurring at electrode/electrolyte interfaces, and has been widely applied to the analysis of the insertion/desertion process of lithium ion in the intercalation electrode for lithium ion battery. In this paper, the ascription of each time constant of the EIS spectra is discussed, based on the analysis of the common EIS features of intercalation electrode. The kinetic parameters in the lithium ion insertion/desertion，dependent on temperature and electrode polarization, such as the charge transfer resistance, the electronic resistance of activated material, the resistance of SEI film that lithium ion transferring through, are also discussed based on the theoretical analysis.

Contents
1 Introduction
2 The common EIS features of intercalation electrode
3 The analysis of electrochemical impedance spectroscopy
3.1 The analysis of high-frequency arc
3.2 The analysis of medium to high-frequency arc
3.3 The analysis of medium -frequency arc
3.4 The analysis of low-frequency straight line
3.5 The analysis of the lowest-frequency domain
4 Conclusion

Key words: lithium-ion batteries, EIS, SEI films, electronic conductivity, charge transfer resistance

CLC Number: 

[1] Guohui Zhu, Hongxian Huan, Dawei Yu, Xueyi Guo, Qinghua Tian. Selective Recovery of Lithium from Spent Lithium-Ion Batteries [J]. Progress in Chemistry, 2023, 35(2): 287-301.
[2] Caiwei Wang, Dongjie Yang, Xueqing Qiu, Wenli Zhang. Applications of Lignin-Derived Porous Carbons for Electrochemical Energy Storage [J]. Progress in Chemistry, 2022, 34(2): 285-300.
[3] Yang Chen, Xiaoli Cui. Titanium Dioxide Anode Materials for Lithium-Ion Batteries [J]. Progress in Chemistry, 2021, 33(8): 1249-1269.
[4] Jiasheng Lu, Jiamiao Chen, Tianxian He, Jingwei Zhao, Jun Liu, Yanping Huo. Inorganic Solid Electrolytes for the Lithium-Ion Batteries [J]. Progress in Chemistry, 2021, 33(8): 1344-1361.
[5] Jinhuo Gao, Jiafeng Ruan, Yuepeng Pang, Hao Sun, Junhe Yang, Shiyou Zheng. High Temperature Properties of LiNi0.5Mn1.5O4 as Cathode Materials for High Voltage Lithium-Ion Batteries [J]. Progress in Chemistry, 2021, 33(8): 1390-1403.
[6] Guoyong Huang, Xi Dong, Jianwei Du, Xiaohua Sun, Botian Li, Haimu Ye. High-Voltage Electrolyte for Lithium-Ion Batteries [J]. Progress in Chemistry, 2021, 33(5): 855-867.
[7] Jinglun Wang, Qin Ran, Chongyu Han, Zilong Tang, Qiduo Chen, Xueying Qin. Organosilicon Functionalized Electrolytes for Lithium-Ion Batteries [J]. Progress in Chemistry, 2020, 32(4): 467-480.
[8] Guange Wang, Huaning Zhang, Tong Wu, Borui Liu, Qing Huang, Yuefeng Su. Recycling and Regeneration of Spent Lithium-Ion Battery Cathode Materials [J]. Progress in Chemistry, 2020, 32(12): 2064-2074.
[9] Wuwei Yan, Yongning Liu, Shaokun Chong, Yaping Zhou, Jianguo Liu, Zhigang Zou. Lithium-Rich Cathode Materials for High Energy-Density Lithium-Ion Batteries [J]. Progress in Chemistry, 2017, 29(2/3): 198-209.
[10] Shi Jingjing, Guo Xing, Chen Renjie, Wu Feng. Recent Progress in Flexible Battery [J]. Progress in Chemistry, 2016, 28(4): 577-588.
[11] Chen Ruwen, Tu Xinman, Chen Dezhi. Transition Metal Nitrides for Lithium-Ion Batteries [J]. Progress in Chemistry, 2015, 27(4): 416-423.
[12] Liu Xin, Zhao Hailei, Xie Jingying, Lv Pengpeng, Wang Ke, Cui Jiajia. SiOx(0<x≤2) Based Anode Materials for Lithium-Ion Batteries [J]. Progress in Chemistry, 2015, 27(4): 336-348.
[13] Li Xiaopei, Huang Kun, Lin Jieyuan, Xu Yizhuang, Liu Huizhou. Hofmeister Ion Series and Its Mechanism of Action on Affecting the Behavior of Macromolecular Solutes in Aqueous Solution [J]. Progress in Chemistry, 2014, 26(08): 1285-1291.
[14] Liu Weiqing, Kou Dongxing, Cai Molang, Hu Linhua, Dai Songyuan. Impedance Characteristics of Dye Sensitized Solar Cells [J]. Progress in Chemistry, 2012, 24(05): 722-736.
[15] Qin Xueying, Wang Jinglun, Zhang Lingzhi. Organosilicon Based Electrolytes for Lithium-Ion Batteries [J]. Progress in Chemistry, 2012, 24(05): 810-822.