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Progress in Chemistry 2010, Vol. 22 Issue (04): 727-733 Previous Articles   Next Articles

• Invited Article •

Formation Mechanism of Secondary Organic Aerosols from the Reaction of Volatile and Semi-Volatile Compounds

Xie Shaodong**; Tian Xiaoxue   

  1. （Department of Environmental Science, Peking University, Beijing 100871, China）
  • Received: Revised: Online: Published:
  • Contact: Xie Shaodong E-mail:sdxie@pku.edu.cn
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The main physical-chemical processes of secondary organic aerosols (SOA) formation from volatile and semi-volatile compounds can be summarized as photooxidation mechanism, nucleation process, condensation, gas/particle partition and heterogeneous reaction mechanism according to the research about SOA formation mechanism of the last twenty years. These physical-chemical processes and their influence factors are discussed in detail in this paper. Isoprene and toluene and its homologs are focused to illustrate the photooxidation of alkene and aromatic compounds. Two important theories of gas/particle partition, absorption mechanism and adsorption mechanism are analyzed. Heterogeneous reaction is proposed for its substantial effect for SOA formation. At last, some prospects for the study direction of the formation mechanism of SOA are given.

Contents
1 Introduction
2 Main physical and chemical processes of SOA formation
3 Photooxidation mechanism
3.1 Photooxidation mechanism of alkenes
3.2 Photooxidation mechanism of aromatic compounds 
4 Nucleation process, condensation, gas/particle partition 
5 Heterogeneous reaction mechanism 
6 Prospects

Key words: secondary organic aerosols(SOA), photooxidation, volatile organic compounds, nucleation, gas/particle partition, heterogeneous reaction

CLC Number: 

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