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Progress in Chemistry 2010, Vol. 22 Issue (04): 669-676 Previous Articles   Next Articles

• Invited Article •

Cyclodextrin-Based Highly Branched Polymers

Tian Wei; Fan Xiaodong**; Kong Jie; Liu Yuyang; Zhang Weihong   

  1. (Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an 710072, China)
  • Received: Revised: Online: Published:
  • Contact: Fan Xiaodong E-mail:xfand@126.com
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Both of cyclodextrins (CDs) and highly branched polymers including hyperbranched and dendrimers possess molecule cavities in their architectures. Therefore, if the combination of two types of molecular cavities can be obtained in a common polymer structure, it will not only possess some interesting characters in the research of relationship between properties and structure, but also may endow some important applications in various fields, such as inclusion technologies, drug delivery system and gene delivery. In this paper, the investigations and applications on the combination of CDs and highly branched polymers are summarized according to the different combination types. The main content includes five aspects as follow: (1) highly branched polymers with a cyclodextrin core; (2) highly branched polymers carrying cyclodextrins as the pendent groups; (3) inclusion complexation between the interior core, terminal Group or monomer of highly branched polymers and cyclodextrins; (4) highly branched polymers from the self-assembly of cyclodextrins; (5) hyperbranched polymers based on the functional cyclodextrin monomers. In addition, new research trends are expected based on the progress of this kind of polymer.

Contents
1 Introduction
2 Highly branched polymers with a cyclodextrin core
3 Highly branched polymers carrying cyclodextrins as the pendent groups
4 Inclusion complexation between the interior core, terminal group or monomer of highly branched polymers and cyclodextrins
5 Highly branched polymers from the self-assembly of cyclodextrins
6 Hyperbranched polymers based on the functional cyclodextrin monomers
7 Conclusion and outlook

Key words: cyclodextrin, cyclodextrin polymers, highly branched polymers, hyperbranched polymers, dendrimers

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