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Progress in Chemistry 2010, Vol. 22 Issue (04): 663-668 Previous Articles   Next Articles

• Invited Article •

Atom Transfer Radical Polymerization in Miniemulsion

Qian Tao1; Wang Juanjuan2; Zhang Qinghua1**; Zhan Xiaoli1; Chen Fengqiu1   

  1. (1.Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China; 2.College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, China)
  • Received: Revised: Online: Published:
  • Contact: Zhang Qinghua E-mail:qhzhang@zju.edu.cn
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Recent progress in atom transfer radical polymerization(ATRP) in miniemulsion is reviewed in terms of different initiator systems such as normal ATRP, reverse　ATRP, simultaneous reverse and normal initiation(SN&NI)　ATRP　and activator generated by electron transfer(AGET) ATRP. The system of normal ATRP in miniemulsion is unstable. Reverse initiation system is fit for polymerization in miniemulsion, but large amount of surfactant is used. Though small amount of catalyst is used in　SN&NI system, polymerization still keeps well controlled. Electronic transfer reaction is used in AGET ATRP to reduce oxide state of transition metal, in which no initiator is needed unlike the SN＆NI system.

Contents
1 Introduction
2 Normal atom transfer radical polymerization
3 Reverse atom transfer radical polymerization
4 Simultaneous reverse and normal initiation(SN&NI) ATRP
5 Activator generated by electron transfer(AGET) ATRP
6 Conclusion

Key words: tom transfer radical polymerization (ATRP), miniemulsion, initiator, living radical polymerization

CLC Number: 

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