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Progress in Chemistry 2010, Vol. 22 Issue (04): 654-662 Previous Articles   Next Articles

• Invited Article •

Dilute Acid Hydrolysis Reaction of Biomass Hemicellulose

Jin Qiang1,2; Zhang Hongman3; Yan Lishi1,2; Huang He1,2**   

  1. (1.College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing 210009, China；2.State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China；3.College of Science, Nanjing University of Technology, Nanjing 210009, China)
  • Received: Revised: Online: Published:
  • Contact: Huang He E-mail:biotech@njut.edu.cn
  • Supported by:

    National Natural Science Foundation of China

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Hemicellulose is the second largest component of lignocellulosic biomass. The conversion of hemicellulose with high efficiency and low costs is a key technology to industrial lignocellulosic biomass conversion process. Dilute acid hydrolysis technology is widely used in biomass hemicellulose hydrolysis. It has the advantages of high efficiency for hemicellulosic sugar conversion, and the obtained sugar can be used to produce fuel ethanol further. Hemicellulose can be also hydrolyzed directly to produce functional food such as oligosaccharides and chemical products such as furfural. In this paper, the progress of hemicellulose hydrolysis reaction with dilute acid is reviewed. The basic structure characterization of hemicellulose is introduced. The mechanism of the dilute acid catalytic hydrolysis reaction and reaction networks are discussed. The influences of different catalysts and reaction conditions on the target products are remarked. The hemicellulose hydrolysis kinetic models are summarized. The paper also indicates the future research trend of hemicellulose dilute acid hydrolysis reaction and utilization for its hydrolysates.

Contents
1 Introduction
2 Structure and characterization of hemicellulose
3 Dilute acid hydrolysis mechanism and reaction network of hemicellulose
4 Factors influencing hemicellulose hydrolysis reaction with dilute acid
5 Dilute acid hydrolysis kinetic models of hemicellulose
6 Conclusion and prospects

Key words: hemicellulose, hydrolysis reaction, kinetics, fuel ethanol

CLC Number: 

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