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Progress in Chemistry 2010, Vol. 22 Issue (01): 71-80 Previous Articles   Next Articles

• Invited Article •

Indium Reagent Mediated Reactions in Aqueous Media and Their Applications in Organic Synthesis

Du Zhengyin**;  Li Yanchun   

  1. (College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China)
  • Received: Revised: Online: Published:
  • Contact: Du Zhengyin E-mail:zhengyin_du@nwnu.edu.cn
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Much attention has been focused on metal indium and indium salt mediated aqueous reactions due to their high reactivity, nontoxicity, good stability in water and in air. Moreover, many functional groups can not be affected in the indium reagent-mediated organic transformations because of the low heterophilicity of indium, which results that indium reagents are commonly regarded as oriented reagents in organic synthesis. In this paper, the organic transformations mediated by metal indium, indium salt and organoindium reagents in aqueous media in recent years are reviewed. The new types and the advantages of reactions have been introduced. The recent advances of these reactions are summarized and the future orientations of indium reagent mediated reactions in water phase are presented.

Contents
1 Introduction
2 Indium-mediated chemical reaction in aqueous media
2.1 Allylation reactions
2.2 Propargylation and allenylation reaction
2.3 Aldol reaction
2.4 Reductive cyclization reactions
2.5 Miscellaneous reactions
3 Indium salt-mediated chemical reactions in aqueous media
3.1 Indium (Ⅲ) halide mediated aqueous phase reactions
3.2 In(OTf)3 mediated aqueous phase reactions
3.3 In(OAc)3 mediated aqueous phase reactions
4 Organoindium reagents involved chemical reactions in aqueous media
5 Conclusion

Key words: metal indium, organoindium reagent, organic synthesis, aqueous phase reaction, environmentally-friendly reaction

CLC Number: 

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