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Progress in Chemistry 2010, Vol. 22 Issue (01): 32-43 Previous Articles   Next Articles

• Invited Article •

Preparation and Application of Mesoporous Alumina

Yang Ling;  Feng Xuan;  Liu Yingliang**   

  1. (Department of Chemistry, Jinan University, Guangzhou 510632, China)
  • Received: Revised: Online: Published:
  • Contact: Liu Yingliang E-mail:tliuyl@jnu.edu.cn
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This paper has reviewed recent progress in preparation, characterization and application of mesoporous alumina (MA). We introduce the preparation methods of MA contrastively and respectively, and overview the post treatment method of precursors. Subsequently, by contrasting the average pore size, specific surface areas and morphology of MA, we discuss the influence factors on the preparation and thermal stability of MA, which involve preparation method, aluminum sources, template, reactant ratio, pH value, post treatment method of precursors and so on. In addition, analysis and characterization methods utilized in preparation of MA, including transmission electron microscopy(TEM) and selected area electron diffraction(SAED), X-ray powder diffraction(XRD) and low angle X-ray powder diffraction(LAXRD), gas adsorption-desorption method, different thermal and thermo gravimetry analysis(DT-TGA) and 27Al magic angle spinning nuclear magnetic resonance(27Al MAS NMR), are introduced in detail. Meanwhile, the development trend of preparation and application of MA for the field of catalytic, adsorption, optics and other fields is prospected.

Contents
1 Introduction
2 Preparation methods of MA
2.1 Hydrothermal method
2.2 Sol-gel method
2.3 Precipitation method
2.4 Micro-emulsion method
2.5 Ionic liquid method
2.6 Hard template method
2.7 Other methods and some combinatory methods
2.8 Post treatment method
3 Influence factors in preparation of MA and thermal stability of MA
3.1 Influence of different reaction conditions
3.2 Thermal stability of MA
3.3 Control of morphology
4 Analysis and characterization methods
4.1 Transmission electron microscope (TEM) and selected area electron diffraction(SAED)
4.2 X-ray powder diffraction (XRD) and low angle X-ray powder diffraction (LAXRD)
4.3 Gas adsorption-desorption method
4.4 Different thermal and thermo gravimetry analysis (DT-TGA)
4.5 27Al magic angle spinning nuclear magnetic resonance (27Al MAS NMR)
5 Application of MA
5.1 Application in catalytic field
5.2 Application in adsorption field
5.3 Application in optical field
5.4 Application in other fields
6 Prospects

Key words: mesoporous alumina, preparation, thermal stability, specific surface area

CLC Number: 

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